Alternation of traditional cement mortars using fly ash-based geopolymer mortars modified by slag

被引:137
作者
Shang, Jun [1 ,2 ]
Dai, Jian-Guo [3 ]
Zhao, Tie-Jun [1 ,2 ]
Guo, Si-Yao [1 ,2 ]
Zhang, Peng [1 ,2 ]
Mu, Ben [1 ,2 ]
机构
[1] Qingdao Univ Technol, Sch Civil Engn, Qingdao 266033, Peoples R China
[2] Collaborat Innovat Ctr Engn Construct & Safety Sh, Qingdao 266033, Peoples R China
[3] Hong Kong Polytech Univ, Dept Civil & Environm Engn, Hong Kong 999077, Hong Kong, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金; 美国国家科学基金会;
关键词
Alkali activated materials; Slag; Fly ash; Service property; Durability; Sustainability; ALKALI-ACTIVATED MATERIALS; ACCELERATED CARBONATION; PHOSPHATE CEMENT; PORTLAND-CEMENT; PHASE EVOLUTION; BINDERS; TEMPERATURE; SHRINKAGE; HYDRATION; DESIGN;
D O I
10.1016/j.jclepro.2018.08.255
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The use of local aluminosilicates to serve the local engineering applications could resolve the issue of unpredicted properties of the geopolymer caused by the wide variance in aluminosilicates reactivity. The locally available aluminosilicate byproducts (e.g., fly ash [FA] and granulated ground blast-furnace slag [GGBS]) in Qingdao were used to synthesize geopolymer cement in this study. Six geopolymer cement mortars with different FA/GGBS ratios were compared with ordinary Portland cement (OPC) and magnesium potassium phosphate cement (MKPC) mortars in terms of workability, setting time, strength development, volume stability and chloride permeability. The use of high volume of GGBS equips the geopolymer mortars with fast setting and high early strength despite poor volume stability. Thus, GGBS geopolymer mortars could potentially replace the high-cost MKPC mortar for rapid rehabilitation in construction. The geopolymer cement mortar with a FA/GGBS ratio of 4 behaves similar to OPC mortars in terms of fluidity, setting time, strength development, volume stability and chloride permeability. Therefore, FA-based geopolymer mortar blended with 20% GGBS could be considered as a high-efficiency, low-cost, eco-friendly and sustainable replacement of OPC mortar. Overall, the geopolymer cement properties could be engineered based on the FA/GGBS ratio in order to serve local engineering applications for the maximum utilization in different scenarios. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码:746 / 756
页数:11
相关论文
共 47 条
[1]   Mix design, properties and cost analysis of fly ash-based geopolymer foam [J].
Abdollahnejad, Z. ;
Pacheco-Torgal, F. ;
Felix, T. ;
Tahri, W. ;
Barroso Aguiar, J. .
CONSTRUCTION AND BUILDING MATERIALS, 2015, 80 :18-30
[2]  
[Anonymous], 1990, Cement and Concrete Research, DOI [DOI 10.1016/0008-8846(90)90083-A, 10.1016/0008-8846(90)90083-A]
[3]   Recycled aggregate from C&D waste & its use in concrete - A breakthrough towards sustainability in construction sector: A review [J].
Behera, Monalisa ;
Bhattacharyya, S. K. ;
Minocha, A. K. ;
Deoliya, R. ;
Maiti, S. .
CONSTRUCTION AND BUILDING MATERIALS, 2014, 68 :501-516
[4]   Influence of slag chemistry on the hydration of alkali-activated blast-furnace slag - Part I: Effect of MgO [J].
Ben Haha, M. ;
Lothenbach, B. ;
Le Saout, G. ;
Winnefeld, F. .
CEMENT AND CONCRETE RESEARCH, 2011, 41 (09) :955-963
[5]   MgO content of slag controls phase evolution and structural changes induced by accelerated carbonation in alkali-activated binders [J].
Bernal, Susan A. ;
Nicolas, Rackel San ;
Myers, Rupert J. ;
Mejia de Gutierrez, Ruby ;
Puertas, Francisca ;
van Deventer, Jannie S. J. ;
Provis, John L. .
CEMENT AND CONCRETE RESEARCH, 2014, 57 :33-43
[6]   Gel nanostructure in alkali-activated binders based on slag and fly ash, and effects of accelerated carbonation [J].
Bernal, Susan A. ;
Provis, John L. ;
Walkley, Brant ;
Nicolas, Rackel San ;
Gehman, John D. ;
Brice, David G. ;
Kilcullen, Adam R. ;
Duxson, Peter ;
van Deventer, Jannie S. J. .
CEMENT AND CONCRETE RESEARCH, 2013, 53 :127-144
[7]   Friedel's salt, Ca2Al(OH)6(Cl,OH)•2H2O:: Its solid solutions and their role in chloride binding [J].
Birnin-Yauri, UA ;
Glasser, FP .
CEMENT AND CONCRETE RESEARCH, 1998, 28 (12) :1713-1723
[8]   Resources and waste management in Turin (Italy): the role of recycled aggregates in the sustainable supply mix [J].
Blengini, Gian Andrea ;
Garbarino, Elena .
JOURNAL OF CLEANER PRODUCTION, 2010, 18 (10-11) :1021-1030
[9]   A review of the multi-component utilisation of coal fly ash [J].
Blissett, R. S. ;
Rowson, N. A. .
FUEL, 2012, 97 :1-23
[10]   Composition and microstructural changes of cement pastes upon heating, as studied by neutron diffraction [J].
Castellote, M ;
Alonso, C ;
Andrade, C ;
Turrillas, X ;
Campo, J .
CEMENT AND CONCRETE RESEARCH, 2004, 34 (09) :1633-1644