Regiospecific C-H Bond Activation: Reactivity Study of N-Heterocyclic Silylene toward Ambidentate Phosphorus Ylide

被引：25

作者：

Azhakar, Ramachandran ^{[1
]}

Sarish, Sankaranarayana Pillai ^{[1
]}

Roesky, Herbert W. ^{[1
]}

Hey, Jakob ^{[1
]}

Stalke, Dietmar ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

ORGANOMETALLICS | 2011年 / 30卷 / 11期

关键词：

STABLE SILYLENE; OXIDATIVE ADDITION; METAL-COMPLEXES; CARBENE; LIGAND; SILICON(II); CRYSTAL; CHEMISTRY; PH2P(CH2PY)(NSIME3); DICHLOROSILYLENE;

D O I：

10.1021/om200308u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of two highly reactive species, the silylene [CH{C(Me)NAr}-{C(=CH2)NAr}Si] (L, Ar = 2,6-iPr(2)C(6)H(3)) and the phosphorus ylide MeC(O)CHPPh3, resulted in the formation of 1, involving regiospecific C-alkyl-H bond activation. Compound 1 was characterized by elemental analysis and multinuclear NMR and unambiguously by single-crystal X-ray structural analysis.

引用

页码：2897 / 2900

页数：4

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