Recent Advances in Enhanced Performance of Ni-Rich Cathode Materials for Li-Ion Batteries: A Review

被引:28
作者
Butt, Annam [1 ]
Ali, Ghulam [2 ]
Kubra, Khadija Tul [1 ,3 ]
Sharif, Rehana [1 ]
Salman, Ayesha [1 ]
Bashir, Muzaffar [4 ]
Jamil, Sidra [5 ]
机构
[1] Univ Engn & Technol, Dept Phys, Lahore 54890, Pakistan
[2] Natl Univ Sci & Technol NUST, USPCAS E, H-12, Islamabad 44000, Pakistan
[3] Univ Engn & Technol, Laser & Optron Ctr, Lahore 54890, Pakistan
[4] Univ Punjab, Dept Phys, Lahore 54590, Pakistan
[5] Southwest Univ, Minist Educ, Sch Mat & Energy, Lab Lumininescence Anal & Mol Sensing, Chongqing 400715, Peoples R China
关键词
coating; degradation mechanisms; doping; Ni-rich cathode materials; LAYERED OXIDE CATHODES; HIGH-ENERGY-DENSITY; HIGH-VOLTAGE PERFORMANCE; TRANSITION-METAL OXIDE; DUAL-CONDUCTIVE LAYERS; IMPROVED ELECTROCHEMICAL PERFORMANCES; POSITIVE ELECTRODE MATERIALS; SUPERIOR CYCLING STABILITY; SOLID-STATE CHEMISTRY; HIGH CUTOFF VOLTAGE;
D O I
10.1002/ente.202100775
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
High energy Li-ion batteries (LIBs) have garnered substantial consideration in recent years for their utilization in many fields like communication, transportation, and aviation. As the cathode is the crucial component of LIBs, so by enhancing its electrochemical performance, the capacity, rate capability, as well as cyclability of batteries can be enhanced. Ni-rich cathode materials (LiNi x Mn y Co1-x-y O2, x >= 0.5) have been accredited for their benefits in enhanced capacity, high working voltage, and low manufacturing cost. The high Ni content is accountable for the exceptional capacity but the utilization in the commercialized LIBs is mired by their electrochemical cycling issues like capacity fading, voltage decay, and safety hazard. To overcome these obstructions, a variety of methodologies have been adopted like doping, coating, and comodification of these cathode materials. An inclusive study of Ni-rich cathode materials, their degradation mechanism, and the strategies is conferred, which have been employed in recent years to overcome the challenges faced by these materials in their commercialization.
引用
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页数:33
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