Synthesis, electrochemistry, and spectroscopy of blue platinum(II) polyynes and diynes

被引：0

作者：

Younus, M

Köhler, A

Cron, S

Chawdhury, N

Al-Mandhary, MRA

Khan, MS

Lewis, J

Long, NJ

Friend, RH

Raithby, PR

机构：

[1] Univ Cambridge, Chem Lab, Cambridge CB2 1EW, England

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[3] Univ Cambridge, Cavendish Lab, Cambridge CB3 0HE, England

[4] Sultan Qaboos Univ, Coll Sci, Al Khoud 123, Oman

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1998年 / 37卷 / 21期

关键词：

diyne complexes; electrochemistry; platinum; polymers; UV/Vis spectroscopy;

D O I：

10.1002/(SICI)1521-3773(19981116)37:21<3036::AID-ANIE3036>3.0.CO;2-R

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The smallest band gap observed so far (1.77 eV) for an organometallic polymer is exhibited by the blue, rigid-rod polymer 2, which is prepared by the reaction of trans-[PtCl2(PnBu3)2] with one equivalent of 1.

引用

页码：3036 / 3039

页数：4

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