Synthesis, electrochemistry, and spectroscopy of blue platinum(II) polyynes and diynes

被引：0
|
作者：
Younus, M
Köhler, A
Cron, S
Chawdhury, N
Al-Mandhary, MRA
Khan, MS
Lewis, J
Long, NJ
Friend, RH
Raithby, PR
机构：
[1] Univ Cambridge, Chem Lab, Cambridge CB2 1EW, England
[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
[3] Univ Cambridge, Cavendish Lab, Cambridge CB3 0HE, England
[4] Sultan Qaboos Univ, Coll Sci, Al Khoud 123, Oman
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1998年 / 37卷 / 21期
关键词：
diyne complexes; electrochemistry; platinum; polymers; UV/Vis spectroscopy;
D O I：
10.1002/(SICI)1521-3773(19981116)37:21<3036::AID-ANIE3036>3.0.CO;2-R
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The smallest band gap observed so far (1.77 eV) for an organometallic polymer is exhibited by the blue, rigid-rod polymer 2, which is prepared by the reaction of trans-[PtCl2(PnBu3)2] with one equivalent of 1.
引用
收藏
页码：3036 / 3039
页数：4
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