Synthesis, X-ray structure and 199Hg, 77Se CP MAS NMR studies on the first tris(imidazolidine-2-selone) mercury complex:: {Chloro-tris[N-methyl-2(3H)-imidazolidine-2-selone] mercury(II)} chloride

被引：15

作者：

Al-Amri, AHD ^{[1
]}

Fettouhi, M ^{[1
]}

Wazeer, MIM ^{[1
]}

Isab, AA ^{[1
]}

机构：

[1] King Fahd Univ Petr & Minerals, Dept Chem, Dhahran 31261, Saudi Arabia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 12期

关键词：

crystal structure; CP MAS Hg-199 NMR; Se-77; NMR; N-methyl-imidazolidine-2-selone; Hg(II) complex;

D O I：

10.1016/j.inoche.2005.09.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel cationic Hg(II) complex has been synthesized with N-methyl-imidazolidine-2-selone ligand. The tris(N-Methyl-imidazolidine2-selone) mercury(II) complex, [(MeIMSe)(3)HgCl]Cl-+(-) (1), has been characterized by single crystal X-ray analysis and CP MAS Hg-199 and Se-77 NMR. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1109 / 1112

页数：4

共 17 条

[1] Recent studies in the coordination chemistry of heterocyclic thiones and thionates [J].

Akrivos, PD .

COORDINATION CHEMISTRY REVIEWS, 2001, 213 :181-210

[2] Complexes of heterocyclic thiones and Group 12 metals -: Part 3.: Preparation and characterisation of 1:2 complexes of mercury(II) halides with 1-methylimidazoline-2(3H)-thione:: the crystal structures of [(HgX2)(1-methylimidazoline-2(3H)-thione)2] (X = Cl, Br, I) at 160 K [J].

Bell, NA ;

Branston, TN ;

Clegg, W ;

Creighton, JR ;

Cucurull-Sánchez, L ;

Elsegood, MRJ ;

Raper, ES .

INORGANICA CHIMICA ACTA, 2000, 303 (02) :220-227

[3] Solid-state 199Hg MAS NMR studies of mercury(II) thiocyanate complexes and related compounds.: Crystal structure of Hg(SeCN)2 [J].

Bowmaker, GA ;

Churakov, AV ;

Harris, RK ;

Howard, JAK ;

Apperley, DC .

INORGANIC CHEMISTRY, 1998, 37 (08) :1734-1743

[4] SELENIUM-MERCURY INTERACTION - SYNTHESIS, SPECTROSCOPIC AND X-RAY STRUCTURAL STUDIES OF METHYLMERCURY-SELENOUREA COMPLEXES [J].

CARTY, AJ ;

MALONE, SF ;

TAYLOR, NJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 172 (02) :201-211

[5] CP/MAS SE-77 NMR IN SOLIDS - CHEMICAL-SHIFT TENSORS AND ISOTROPIC SHIFTS [J].

COLLINS, MJ ;

RATCLIFFE, CI ;

RIPMEESTER, JA .

JOURNAL OF MAGNETIC RESONANCE, 1986, 68 (01) :172-179

[6] COMPLEXES OF ZINC(II), CADMIUM(II) AND MERCURY(II) HALIDES WITH ETHYLENESELENOUREA [J].

DEVILLANOVA, FA ;

VERANI, G .

TRANSITION METAL CHEMISTRY, 1977, 2 (01) :9-11

[7] Structural chemistry of complexes of (n-1)d10 nsm metal ions with (β-N-donor substituted thiolate ligands (m=0, 2) [J].

Fleischer, H .

COORDINATION CHEMISTRY REVIEWS, 2005, 249 (7-8) :799-827

[8] SOLID-STATE HG-199 NMR OF HEXAKIS(DIMETHYL-SULFOXIDE)MERCURY(II) TRIFLUOROMETHANESULFONATE - A NEW STANDARD FOR HG-199 CP/MAS EXPERIMENTS [J].

HOOK, JM ;

DEAN, PAW ;

VANGORKOM, LCM .

MAGNETIC RESONANCE IN CHEMISTRY, 1995, 33 (01) :77-79

[9] The preparation, characterization, and X-ray structural analysis of dichlorobis[1-methyl-3-(2-propyl)-2(3H)imidazolethione]mercury(II) [J].

Hutchings, AM ;

McConnell, NE ;

Faucher, RA ;

VanDerveer, D ;

Williams, DJ .

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2003, 33 (08) :619-623

[10] NMR IN ROTATING SOLIDS [J].

MARICQ, MM ;

WAUGH, JS .

JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (07) :3300-3316

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