Process Optimisation of In Situ H2 Generation From Ammonia Using Ni on Alumina Coated Cordierite Monoliths

被引：10
|
作者：
Plana, Carlos [1 ]
Armenise, Sabino [1 ,2 ]
Monzon, Antonio [2 ]
Garcia-Bordeje, Enrique [1 ]
机构：
[1] Inst Carboquim CSIC, Zaragoza 50018, Spain
[2] Univ Zaragoza, Dept Chem & Environm Engn, Inst Nanosci Aragon, Zaragoza 50018, Spain
来源：
TOPICS IN CATALYSIS | 2011年 / 54卷 / 13-15期
关键词：
Ni catalyst; Monolith; Alumina support; Ammonia decomposition; H-2; generation; DISPERSED NI/AL2O3 CATALYSTS; COX-FREE HYDROGEN; NH3; DECOMPOSITION; PROMOTED RU; KINETICS; STORAGE;
D O I：
10.1007/s11244-011-9706-x
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A catalyst of Ni supported on alumina coated monolith has been prepared, characterized and tested in NH3 decomposition. The characterization of the catalyst by XPS and TPR showed that there is no formation of aluminates after catalyst use. It is studied the effect of the space velocity, by varying the feed flow rate and the catalyst's length. Some evidences are shown about the reaction inhibition by produced H-2 and about the reasons for the better performance of the monolith than packed bed catalyst.
引用
收藏
页码：914 / 921
页数：8
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