Spinodally decomposed nanostructures in a TiO2-VO2 crystal

We have prepared a single crystal of Ti0.4V0.6O2 which forms a solid solution crystallizing in the rutile structure at high temperatures and undergoes phase separation due to the spinodal decomposition when cooled to room temperature. The spinodally decomposed crystal consists of a self-assembled, mega stack of alternate Ti- and V-rich layers with an approximate period of 33 nm along the c axis. The unidirectional microstructure causes a large anisotropy in resistivity and a small one in thermal conductivity. A sharp metal-insulator transition as well as a structural transition to a monoclinic structure is observed in the thin V-rich layers. (C) 2015 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution 3.0 Unported License.