Ba1-xSrxTiO3 solid solutions prepared by a solid-state reaction in air at 1200-1400 degrees C, followed by slow cooling to room temperature at the end of the reaction, were essentially oxygen-stoichiometric and p-type. Their conductivity increased reversibly when either p(O-2) in the surrounding atmosphere was increased or a dc bias as small as 1 V was applied across the samples. The enhanced p-type conductivity is attributed to the creation of mobile holes on underbonded oxide ions. The same samples quenched from >similar to 1400 degrees C were increasingly oxygen deficient and n-type. They showed reduced conductivity with either a dc bias or increased p(O-2), attributed to the trapping of mobile electrons. These materials provide a rare example of a switch between n-type and p-type conductivity, in the same material, linked to oxygen stoichiometry variation. In both n- and p-type materials, the samples responded to external stimuli in a way similar to that of a leaky capacitor; polarization processes at sample surfaces led first to charge storage and second to a reversible change in bulk electrical properties.
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Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, SpainUniv Sheffield, Dept Mat Sci & Engn, Sheffield S1 3JD, S Yorkshire, England
Beltran, Hector
Prades, Marta
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Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, SpainUniv Sheffield, Dept Mat Sci & Engn, Sheffield S1 3JD, S Yorkshire, England
Prades, Marta
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Maso, Nahum
Cordoncillo, Eloisa
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Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, SpainUniv Sheffield, Dept Mat Sci & Engn, Sheffield S1 3JD, S Yorkshire, England
Cordoncillo, Eloisa
West, Anthony R.
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Univ Sheffield, Dept Mat Sci & Engn, Sheffield S1 3JD, S Yorkshire, EnglandUniv Sheffield, Dept Mat Sci & Engn, Sheffield S1 3JD, S Yorkshire, England
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Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, SpainUniv Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, Spain
Gil Escrig, Lidon
Prades, Marta
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Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, SpainUniv Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, Spain
Prades, Marta
Beltran, Hector
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Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, SpainUniv Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, Spain
Beltran, Hector
Cordoncillo, Eloisa
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Cordoncillo, Eloisa
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Univ Sheffield, Dept Mat Sci & Engn, Sheffield S1 3JD, S Yorkshire, EnglandUniv Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, Spain
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Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, SpainUniv Sheffield, Dept Mat Sci & Engn, Sheffield S1 3JD, S Yorkshire, England
Beltran, Hector
Prades, Marta
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Prades, Marta
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Cordoncillo, Eloisa
West, Anthony R.
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Univ Sheffield, Dept Mat Sci & Engn, Sheffield S1 3JD, S Yorkshire, EnglandUniv Sheffield, Dept Mat Sci & Engn, Sheffield S1 3JD, S Yorkshire, England
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Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, SpainUniv Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, Spain
Gil Escrig, Lidon
Prades, Marta
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Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, SpainUniv Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, Spain
Prades, Marta
Beltran, Hector
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Beltran, Hector
Cordoncillo, Eloisa
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