Graphene oxide-embedded chitosan/gelatin hydrogel particles for the adsorptions of multiple heavy metal ions

被引:44
作者
Perumal, Suguna [1 ]
Atchudan, Raji [2 ]
Yoon, Dong Ho [3 ]
Joo, Jin [1 ]
Cheong, In Woo [1 ]
机构
[1] Kyungpook Natl Univ, Sch Engn, Dept Appl Chem, Daehak Ro 80, Daegu 41566, South Korea
[2] Yeungnam Univ, Sch Chem Engn, Gyongsan 38541, South Korea
[3] Kuk Il Paper Mfg Co Ltd, R&D Ctr, Baekok Daero 563, Yongin 17128, South Korea
关键词
EFFICIENT REMOVAL; WASTE-WATER; CD(II); HG(II);
D O I
10.1007/s10853-020-04651-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Spherical-shaped graphene oxide-embedded chitosan/gelatin hydrogel particles (CGGO) were prepared by using inverse suspension method from biopolymers chitosan and gelatin with graphene oxide for the adsorption of heavy metal ions (HM). The prepared CGGO particles were characterized by various physicochemical techniques such as field emission scanning electron microscopy, energy-dispersive X-ray spectroscopy analysis, X-ray diffraction, and Fourier transform infrared spectrometry. HM-Pb(II), Cd(II), Hg(II), and Cr(III) adsorption experiments using CGGO showed 55% removal efficiency of Hg(II) in the single metal system. However, in the multiple metal ion system, all metal ions showed removal efficiency > 70%. This suggests that the prepared hydrogel particles can be effectively used for the removal of HM. The preparation method also paves the way for the large-scale production of hydrogel particles as HM adsorbents.
引用
收藏
页码:9354 / 9363
页数:10
相关论文
共 24 条
[1]  
[Anonymous], D4646 ASTM
[2]   Reverse osmosis applied to metal finishing wastewater [J].
Benito, Y ;
Ruíz, ML .
DESALINATION, 2002, 142 (03) :229-234
[3]   Mechanically strong and pH-responsive carboxymethyl chitosan/graphene oxide/polyacrylamide nanocomposite hydrogels with fast recoverability [J].
Chen, Yang ;
Wang, Hongqiu ;
Yu, Junrong ;
Wang, Yan ;
Zhu, Jing ;
Hu, Zuming .
JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION, 2017, 28 (16) :1899-1917
[4]  
Das M. P., 2017, INT J PHARM PHARM SC, V9, P239, DOI [DOI 10.22159/IJPPS.2017V9I9.17618, 10.22159/ijpps.2017v9i9.17618]
[5]   Refocusing on Nonpriority Toxic Metals in the Aquatic Environment in China [J].
Fu, Zhiyou ;
Guo, Wenjing ;
Dang, Zhi ;
Hu, Qing ;
Wu, Fengchang ;
Feng, Chenglian ;
Zhao, Xiaoli ;
Meng, Wei ;
Xing, Baoshan ;
Giesyl, John P. .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2017, 51 (06) :3117-3118
[6]   Engineered Graphite Oxide Materials for Application in Water Purification [J].
Gao, Wei ;
Majumder, Mainak ;
Alemany, Lawrence B. ;
Narayanan, Tharangattu N. ;
Ibarra, Miguel A. ;
Pradhan, Bhabendra K. ;
Ajayan, Pulickel M. .
ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (06) :1821-1826
[7]   Removal of heavy metal ions from pharma-effluents using graphene-oxide nanosorbents and study of their adsorption kinetics [J].
Gopalakrishnan, Arthi ;
Krishnan, Rajasekar ;
Thangavel, Sakthivel ;
Venugopal, Gunasekaran ;
Kim, Sang-Jae .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2015, 30 :14-19
[8]   Synthesis of amino functionalized magnetic graphenes composite material and its application to remove Cr(VI), Pb(II), Hg(II), Cd(II) and Ni(II) from contaminated water [J].
Guo, Xiaoyao ;
Du, Bin ;
Wei, Qin ;
Yang, Jian ;
Hu, Lihua ;
Yan, Liangguo ;
Xu, Weiying .
JOURNAL OF HAZARDOUS MATERIALS, 2014, 278 :211-220
[9]   Recycled chitosan nanofibril as an effective Cu(II), Pb(II) and Cd(II) ionic chelating agent: Adsorption and desorption performance [J].
Liu, Dagang ;
Li, Zehui ;
Zhu, Yi ;
Li, Zhenxuan ;
Kumar, Rakesh .
CARBOHYDRATE POLYMERS, 2014, 111 :469-476
[10]   Graphene oxide-based materials for efficient removal of heavy metal ions from aqueous solution: A review [J].
Liu, Xiaolu ;
Ma, Ran ;
Wang, Xiangxue ;
Ma, Yan ;
Yang, Yongping ;
Zhuang, Li ;
Zhang, Sai ;
Jehan, Riffat ;
Chen, Jianrong ;
Wang, Xiangke .
ENVIRONMENTAL POLLUTION, 2019, 252 :62-73