We report the observation of ferroelectricity in capacitors based on hafnium-zirconium-oxide. Hf0.5Zr0.5O2 thin films of 7.5 to 9.5 nm thickness were found to exhibit ferroelectric polarization-voltage hysteresis loops when integrated into TiN-based metal-insulator-metal capacitors. A remnant polarization of 16 mu C/cm(2) and a high coercive field of 1 MV/cm were observed. Further proof for the ferroelectric nature was collected by quasi-static polarization-voltage hysteresis, small signal capacitance-voltage, and piezoelectric measurements. Data retention characteristics were evaluated by a Positive Up Negative Down pulse technique. No significant decay of the initial polarization state was observed within a measurement range of up to two days. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3636417]
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Samsung Elect, Semicond Res & Dev Ctr, Yongin 449711, Gyeonggi Do, South KoreaSamsung Elect, Semicond Res & Dev Ctr, Yongin 449711, Gyeonggi Do, South Korea
Kim, Kinam
Lee, Sungyung
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Samsung Elect, Semicond Res & Dev Ctr, Yongin 449711, Gyeonggi Do, South KoreaSamsung Elect, Semicond Res & Dev Ctr, Yongin 449711, Gyeonggi Do, South Korea
机构:
Samsung Elect, Semicond Res & Dev Ctr, Yongin 449711, Gyeonggi Do, South KoreaSamsung Elect, Semicond Res & Dev Ctr, Yongin 449711, Gyeonggi Do, South Korea
Kim, Kinam
Lee, Sungyung
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h-index: 0
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Samsung Elect, Semicond Res & Dev Ctr, Yongin 449711, Gyeonggi Do, South KoreaSamsung Elect, Semicond Res & Dev Ctr, Yongin 449711, Gyeonggi Do, South Korea