Ferroelectric Zr0.5Hf0.5O2 thin films for nonvolatile memory applications

被引:453
作者
Mueller, J. [1 ]
Boescke, T. S.
Braeuhaus, D. [2 ]
Schroeder, U. [3 ]
Boettger, U. [2 ]
Sundqvist, J. [1 ]
Kuecher, P. [1 ]
Mikolajick, T. [3 ,4 ]
Frey, L. [5 ]
机构
[1] Fraunhofer Ctr Nanoelect Technol CNT, D-01099 Dresden, Germany
[2] Rhein Westfal TH Aachen, Inst Werkstoffe Elektrotech, D-52074 Aachen, Germany
[3] Namlab gGmbH, D-01187 Dresden, Germany
[4] Tech Univ Dresden, Chair Nanoelect Mat, D-01062 Dresden, Germany
[5] Fraunhofer Inst Integrated Syst & Device Technol, D-91058 Erlangen, Germany
关键词
CAPACITORS;
D O I
10.1063/1.3636417
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report the observation of ferroelectricity in capacitors based on hafnium-zirconium-oxide. Hf0.5Zr0.5O2 thin films of 7.5 to 9.5 nm thickness were found to exhibit ferroelectric polarization-voltage hysteresis loops when integrated into TiN-based metal-insulator-metal capacitors. A remnant polarization of 16 mu C/cm(2) and a high coercive field of 1 MV/cm were observed. Further proof for the ferroelectric nature was collected by quasi-static polarization-voltage hysteresis, small signal capacitance-voltage, and piezoelectric measurements. Data retention characteristics were evaluated by a Positive Up Negative Down pulse technique. No significant decay of the initial polarization state was observed within a measurement range of up to two days. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3636417]
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页数:3
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