Solvothermal synthesis and characterization of a lithium coordination polymer possessing a highly stable 3D network structure

被引：30

作者：

Liu, Ying-Ya ^{[1
,2
]}

Zhang, Han ^{[1
,2
]}

Sun, Li-Xian ^{[1
]}

Xu, Fen ^{[1
]}

You, Wan-Sheng ^{[3
]}

Zhao, Yi ^{[3
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

[3] Liaoning Normal Univ, Fac Chem & Chem Engn, Inst Chem Functionalized Mat, Dalian 116029, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 04期

基金：

中国国家自然科学基金;

关键词：

metal-organic framework; coordination polymer; lithium; solvothermal synthesis;

D O I：

10.1016/j.inoche.2007.12.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solvothermal reaction of lithium perchlorate and 1,4-benzene dicarboxylic acid at 180 degrees C has resulted in a novel lithium coordination polymer Li-2 (CO2-C6H4-CO2), which is characterized by single crystal X-ray diffraction analysis, X-ray powder diffraction analysis, elemental analysis, TGA/DTA and IR spectra. The compound shows a remarkable high thermal stability up to 530 degrees C, features a new 3D network containing two types of 6-membered ring and 18-membered dumbbell-like ring in view from different directions. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：396 / 399

页数：4

共 37 条

[1] 1,4-Benzenedicarboxylate derivatives as links in the design of paddle-wheel units and metal-organic frameworks [J].