A polyoxometalate-based inorganic-organic hybrid material: synthesis, characterization structure and photocatalytic study

被引：4

作者：

Tian, Jingzhi ^{[1
]}

Jing, Tao ^{[1
]}

Zheng, Yongjie ^{[1
]}

机构：

[1] Qiqihar Univ, Coll Chem & Chem Engn, Qiqihar 161000, Peoples R China

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2015年 / 70卷 / 07期

基金：

中国国家自然科学基金;

关键词：

crystalline material; inorganic-organic hybrid; photocatalytic activity; polyoxometalates; SELECTIVE OXIDATION; CATALYSIS; CHEMISTRY;

D O I：

10.1515/znb-2014-0275

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new polyoxometalate (POM)-based inorganic-organic hybrid compound, [Ag-2(bib)(3)][H2SiW12O40] (1), has been hydrothermally synthesized and characterized by routine methods. Single-crystal X-ray diffraction analysis reveals that inorganic supramolecular chains constructed of POM and [Ag-2(bib)(3)] subunits are fused together via the Ag cations forming a 3D supramolecular structure. The structure possesses the moganite-type topology. The photocatalytic properties have been investigated through the oxidative decomposition of Rhodamine-B dye.

引用

页码：461 / 466

页数：6

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