The crystallography of correlated disorder

被引:290
|
作者
Keen, David A. [1 ]
Goodwin, Andrew L. [2 ]
机构
[1] Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England
[2] Univ Oxford, Dept Chem, Inorgan Chem Lab, Oxford OX1 3QR, England
基金
欧洲研究理事会;
关键词
PAIR DISTRIBUTION FUNCTION; DIFFUSE-SCATTERING; X-RAY; MONTE-CARLO; PHASE-TRANSITIONS; CRYSTALS; DYNAMICS; ICE; NANOREGIONS; SIMULATION;
D O I
10.1038/nature14453
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Classical crystallography can determine structures as complicated as multi-component ribosomal assemblies with atomic resolution, but is inadequate for disordered systems-even those as simple as water ice-that occupy the complex middle ground between liquid-like randomness and crystalline periodic order. Correlated disorder nevertheless has clear crystallographic signatures that map to the type of disorder, irrespective of the underlying physical or chemical interactions and material involved. This mapping hints at a common language for disordered states that will help us to understand, control and exploit the disorder responsible for many interesting physical properties.
引用
收藏
页码:303 / 309
页数:7
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