Mild C-H/C-C Activation by Z-Selective Cobalt Catalysis

被引：157

作者：

Zell, Daniel ^{[1
]}

Bu, Qingqing ^{[1
]}

Feldt, Milica ^{[1
]}

Ackermann, Lutz ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, Tammannstr 2, D-37077 Gottingen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 26期

基金：

欧洲研究理事会;

关键词：

C-C cleavage; C-H activation; cobalt; homogeneous catalysis; stereoselectivity; CARBON-CARBON BONDS; N-TYPE REACTIONS; H AMIDATION; COBALT(III)-CATALYZED ARYL; DIRECTED FUNCTIONALIZATION; SITE-SELECTIVITY; DIRECT ARYLATION; ALKYNES; CLEAVAGE; ACCESS;

D O I：

10.1002/anie.201601778

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cationic cobalt complexes enable unprecedented cobalt-catalyzed C-H/C-C functionalizations with unique selectivity features. The versatile cobalt catalyst proved broadly applicable, enabled efficient C-H/C-C cleavage at room temperature, and delivered Z-alkenes with excellent diastereocontrol.

引用

页码：7408 / 7412

页数：5

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