Mild C-H/C-C Activation by Z-Selective Cobalt Catalysis

被引：153

作者：

Zell, Daniel ^{[1
]}

Bu, Qingqing ^{[1
]}

Feldt, Milica ^{[1
]}

Ackermann, Lutz ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, Tammannstr 2, D-37077 Gottingen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 26期

基金：

欧洲研究理事会;

关键词：

C-C cleavage; C-H activation; cobalt; homogeneous catalysis; stereoselectivity; CARBON-CARBON BONDS; N-TYPE REACTIONS; H AMIDATION; COBALT(III)-CATALYZED ARYL; DIRECTED FUNCTIONALIZATION; SITE-SELECTIVITY; DIRECT ARYLATION; ALKYNES; CLEAVAGE; ACCESS;

D O I：

10.1002/anie.201601778

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cationic cobalt complexes enable unprecedented cobalt-catalyzed C-H/C-C functionalizations with unique selectivity features. The versatile cobalt catalyst proved broadly applicable, enabled efficient C-H/C-C cleavage at room temperature, and delivered Z-alkenes with excellent diastereocontrol.

引用

页码：7408 / 7412

页数：5

共 50 条

[1] Cobalt-Catalyzed C-H Activation
Moselage, Marc
Li, Jie
Ackermann, Lutz
ACS CATALYSIS, 2016, 6 (02): : 498 - 525
[2] Bimetallic anchoring catalysis for C-H and C-C activation
Jiang-Fei Li
Yu-Xin Luan
Mengchun Ye
Science China Chemistry, 2021, 64 : 1923 - 1937
[3] Bimetallic anchoring catalysis for C-H and C-C activation
Li, Jiang-Fei
Luan, Yu-Xin
Ye, Mengchun
SCIENCE CHINA-CHEMISTRY, 2021, 64 (11) : 1923 - 1937
[4] Manganese(I)-Catalyzed Dispersion-Enabled C-H/C-C Activation
Meyer, Tjark H.
Liu, Weiping
Feldt, Milica
Wuttke, Axel
Mata, Ricardo A.
Ackermann, Lutz
CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (23) : 5443 - 5447
[5] Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C-H/C-C Activation
Liang, Yu-Feng
Mueller, Valentin
Liu, Weiping
Muench, Annika
Stalke, Dietmar
Ackermann, Lutz
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (32) : 9415 - 9419
[6] Cobalt-Catalyzed Tandem C-H Activation/C-C Cleavage/C-H Cyclization of Aromatic Amides with Alkylidenecyclopropanes
Li, Mingliang
Kwong, Fuk Yee
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (22) : 6512 - 6516
[7] Oxazolinyl-Assisted C-H Amidation by Cobalt(III) Catalysis
Mei, Ruhuai
Loup, Joachim
Ackermann, Lutz
ACS CATALYSIS, 2016, 6 (02): : 793 - 797
[8] Rhodaelectro-Catalyzed C-H and C-C Activation
Qiu, Youai
Zhu, Cuiju
Stangier, Maximilian
Struwe, Julia
Ackermann, Lutz
CCS CHEMISTRY, 2021, 3 (02): : 1529 - 1552
[9] Tandem Catalysis: Alcohol Oxidation and C-C Bond Formation via C-H Bond Activation
Simon, Marc-Olivier
Ung, Gael
Darses, Sylvain
ADVANCED SYNTHESIS & CATALYSIS, 2011, 353 (07) : 1045 - 1048
[10] Metal-Organic Cooperative Catalysis in C-H and C-C Bond Activation
Kim, Dong-Su
Park, Woo-Jin
Jun, Chul-Ho
CHEMICAL REVIEWS, 2017, 117 (13) : 8977 - 9015

← 1 2 3 4 5 →