Iron-facilitated direct oxidative C-H transformation of allyl arenes to alkenyl aldehydes

被引：15
|
作者：
Wang, Teng [1 ,2 ]
Xiang, Shi-Kai [1 ]
Qin, Chong [1 ]
Ma, Jun-An [2 ]
Zhang, Li-He [1 ]
Jiao, Ning [1 ,3 ]
机构：
[1] Peking Univ, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
[2] Tianjin Univ, Dept Chem, Tianjin 300072, Peoples R China
[3] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
TETRAHEDRON LETTERS | 2011年 / 52卷 / 25期
基金：
美国国家科学基金会;
关键词：
BOND FUNCTIONALIZATION; TERMINAL ALKENES; AMINATION; ALKYLATION; CATALYST; ACTIVATION; HETEROATOM; MECHANISM; ADJACENT; ETHERS;
D O I：
10.1016/j.tetlet.2011.04.041
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A direct oxidative approach to alkenyl aldehydes from allyl arenes via allyl sp(3) C-H functionalization was disclosed. An inexpensive iron catalyst was employed to facilitate this transformation. The mechanistic studies indicate that the cleavage of the allyl sp(3) C-H bond is involved in the rate-determining step. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3208 / 3211
页数：4
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