All-solid secondary polyaniline-zinc battery

被引：16

作者：

Sivaraman, P. ^{[1
]}

Thakur, A. P. ^{[1
]}

Kushwaha, R. K. ^{[1
]}

Ratna, D. ^{[1
]}

Samui, A. B. ^{[1
]}

机构：

[1] Naval Mat Res Lab, Ambernath 421506, Maharashtra, India

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 2008年 / 38卷 / 02期

关键词：

battery; polyaniline; gel polymer electrolyte; zinc;

D O I：

10.1007/s10800-007-9422-1

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A solid state battery based on polyaniline (PANI), Zinc (Zn) and a gel polymer electrolyte (GPE) is reported for the first time. Poly (ethylene oxide)-zinc sulphate-nanoclay-H2O based GPE was used as the separator. The GPEs with a varying composition of salt were evaluated for their electrochemical performance. The highest conductivity at ambient temperature for the GPEs was found to be 5.54 x 10(-4) S cm(-1). Cyclic voltammetry and impedance studies, with the Zn/GPE/Zn cell, showed reversibility with respect to Zn/Zn2+ couple. The battery showed a capacity of 43.9 Ah kg(-1) of PANI and a coulombic efficiency higher than 100%. However, a decrease in capacity was observed for the system during the cycling.

引用

页码：189 / 195

页数：7

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