Silyl group mediated linkage of closo-C2B10-cage to nido-C2B4-carborane:: synthesis of the novel carborane ligand, 1-R-2-[5′-(SiMe2CH2)-2′,3′-(SiMe3)2-2′,3′-C2B4H5]-1,2-C2B10H10 (R = Me, Ph)

被引：0

作者：

Zhu, YH

Maguire, JA

Hosmane, NS ^{[1
]}

机构：

[1] No Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA

[2] So Methodist Univ, Dept Chem, Dallas, TX 75275 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 10期

关键词：

D O I：

10.1016/j.inoche.2003.07.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the sodium salt of the monoanion, nido-[2,3-(Si(CH3)(3))(2)-2,3-C2B4H5](-), with (chloromethyl)dimethylchlorosilane in a 1:1 molar ratio produced the B-(cage)-substituted cluster, nido-5-ClCH2Si(CH3)(2)-2,3-(Si(CH3)(3))(2)-2,3-C2B4H5 (1), in 81% yield. This product (1) was reacted further with the lithium salt of [closo-1-R-1,2-C2B10H10](-) monoanion (R =Me, Ph) to give the novel linked and mixed C2B4/C2B10 carborane species, 1-Me-2-[5'-SiMe2CH2-2',3'-(SiMe3)(2)-2',3-C2B4H5]-1,2-C2B10H10 (2), 1-Ph-2-[5'-SiMe2CH2-2',3'-(SiMe3)(2)-2',3'-C2B4H5]-1,2-C2B10 (3), in yields of 76% and 81%, respectively. (C) 2003 Elsevier B.V. All rights reserved.

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页码：1344 / 1346

页数：3

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