Factors Influencing the Surface Morphology of Poly(-benzyl L-glutamate)-Block-(Random Coil Polymer) Aggregates Deposited from the Dilute Solution

被引:6
|
作者
Zhu, Guoquan [1 ]
Gao, Qiaochun [1 ]
Li, Zhihe [1 ]
Wang, Fagang [1 ]
机构
[1] Shandong Univ Technol, Sch Mat Sci & Engn, Zibo 255049, Peoples R China
关键词
aggregates; dilute solution; factors; polypeptide block copolymer; surface morphology; L-GLUTAMATE)-GRAFT-POLY(ETHYLENE GLYCOL) COPOLYMER; POLY(GAMMA-BENZYL L-GLUTAMATE) HOMOPOLYMER; POLYPEPTIDE BLOCK-COPOLYMER; POLY(ETHYLENE GLYCOL); SIDE-CHAINS; GRAFT COPOLYMER; MICELLES; BEHAVIOR; NANOPARTICLES; OXIDE);
D O I
10.1080/00914037.2010.504179
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Poly(-benzyl L-glutamate)-block-poly(ethylene glycol) (PBLG-block-PEG, PEG as random coil polymer) was synthesized by a standard N-carboxyl--benzyl-L-glutamate anhydride method. The surface morphology of PBLG-block-PEG copolymer aggregates from the dilute solution was studied by scanning electron microscopy (SEM). The effects of precipitation temperature, precipitation time, various solvent systems, and copolymer solution concentration on the surface morphologies of the polypeptide block copolymer aggregates from the dilute solution were investigated.
引用
收藏
页码:290 / 301
页数:12
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