Optical properties of SnO2 nanostructures prepared via one-step thermal decomposition of tin (II) chloride dihydrate

被引：36
作者：
Al-Gaashani, R. [1 ,2 ]
Radiman, S. [1 ]
Tabet, N. [3 ]
Daud, A. R. [1 ]
机构：
[1] Univ Kebangsaan Malaysia, Fac Sci & Technol, Sch Appl Phys, Bangi 43600, Selangor, Malaysia
[2] Thamar Univ, Fac Sci Appl, Dept Phys, Dhamar, Yemen
[3] King Fand Univ Petr & Minerals, Ctr Res Excellence Renewable Energy, Dhahran, Saudi Arabia
来源：
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS | 2012年 / 177卷 / 06期
关键词：
SnO2; Nanostructures; Thermal decomposition; Optical properties; XPS; THIN-FILMS; OXIDE; NANOPARTICLES; PRECURSOR; NANOCRYSTALS; SURFACE;
D O I：
10.1016/j.mseb.2012.02.006
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
In this study we report on a simple method to synthesize tin dioxide (SnO2) nanostructures through one-step thermal decomposition of tin (II) chloride dihydrate (SnCl2 center dot 2H(2)O) under ambient conditions. The size and morphology of the SnO2 nanostructures can be controlled by changing the temperature and the time of the decomposition process. The structural properties of the products were investigated by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) equipped with energy dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). The optical properties of the samples were studied by UV-vis spectroscopy. The optical gap of the samples was determined from the analysis of the absorbance versus wavelength curves. The results showed that the morphology, the size and the optical gap of the samples varied with the temperature and treatment duration. Crown Copyright (C) 2012 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：462 / 470
页数：9
相关论文
共 41 条
[31]   Synthesis of SnO2 hollow microspheres from ultrasonic atomization and their role in hydrogen sensing [J].
Patil, L. A. ;
Shinde, M. D. ;
Bari, A. R. ;
Deo, V. V. .
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2011, 176 (07) :579-587
[32]   Using nano-QSAR to predict the cytotoxicity of metal oxide nanoparticles [J].
Puzyn, Tomasz ;
Rasulev, Bakhtiyor ;
Gajewicz, Agnieszka ;
Hu, Xiaoke ;
Dasari, Thabitha P. ;
Michalkova, Andrea ;
Hwang, Huey-Min ;
Toropov, Andrey ;
Leszczynska, Danuta ;
Leszczynski, Jerzy .
NATURE NANOTECHNOLOGY, 2011, 6 (03) :175-178
[33]   Synthesis, characterization and optical properties of tin oxide nanoclusters prepared from a novel precursor via thermal decomposition route [J].
Salavati-Niasari, Masoud ;
Mir, Noshin ;
Davar, Fatemeh .
INORGANICA CHIMICA ACTA, 2010, 363 (08) :1719-1726
[34]   Optical properties of SnO2 nanoparticles [J].
Sarmah, Smritimala ;
Kumar, A. .
INDIAN JOURNAL OF PHYSICS, 2010, 84 (09) :1211-1221
[35]  
Sharma A, 2009, J OPTOELECTRON ADV M, V11, P331
[36]   GROWTH OF ZnO NANOSTRUCTURES ON ZINC AND Pt SUBSTRATES [J].
Tabet, N. ;
Faiz, M. ;
Al-Oteibi, A. .
INTERNATIONAL JOURNAL OF NANOSCIENCE, 2007, 6 (01) :23-30
[37]  
Taib H., 2008, J AUST CERAM SOC, V44, P47
[38]   OPTICAL PROPERTIES AND ELECTRONIC STRUCTURE OF AMORPHOUS GERMANIUM [J].
TAUC, J ;
GRIGOROVICI, R ;
VANCU, A .
PHYSICA STATUS SOLIDI, 1966, 15 (02) :627-+
[39]  
Wagner C.D., 1978, HDB XRAY PHOTOELECTR
[40]   Preparation and characterization of SnO2 nanorods by thermal decomposition of SnC2O4 precursor [J].
Xu, CK ;
Xu, GD ;
Liu, YK ;
Zhao, XL ;
Wang, GH .
SCRIPTA MATERIALIA, 2002, 46 (11) :789-794
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