A Practical Copper Catalyzed N-Arylation of Amines Using Aryl Triazenes as Aryl Source

被引：12
|
作者：
Chand, Shiv [1 ]
Kumar, Saurabh [1 ]
Singh, Rahul [1 ]
Singh, Krishna Nand [1 ]
机构：
[1] Banaras Hindu Univ, Inst Sci, Ctr Adv Study, Dept Chem, Varanasi 221005, Uttar Pradesh, India
来源：
CHEMISTRYSELECT | 2019年 / 4卷 / 02期
关键词：
N-Arylation; Aryl triazenes; C-N Bond formation; Copper catalysis; Cross coupling; CROSS-COUPLING REACTIONS; C-N; BOND FORMATION; REDUCTIVE AMINATION; CINNAMIC-ACIDS; BORONIC ACIDS; DECARBOXYLATIVE THIOAMIDATION; ARYLBORONIC ACIDS; HYDROAMINATION; ACTIVATION;
D O I：
10.1002/slct.201803356
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient copper-catalyzed synthesis of N-arylated amines has been developed via cross-coupling of amines with aryl triazenes. The methodology is endowed with broad substrate scope, high yield, and significant functional group tolerance.
引用
收藏
页码：718 / 721
页数：4
相关论文
共 50 条
  • [1] Copper Catalyzed N-Arylation of Amines in Ionic Liquid Using 1-Aryltriazenes as Aryl Surrogates
    Kim, Kang M.
    Kim, Kang Min
    CHEMISTRYSELECT, 2021, 6 (11): : 2709 - 2715
  • [2] Efficient Iron-Catalyzed N-Arylation of Aryl Halides with Amines
    Guo, Diliang
    Huang, He
    Xu, Jinyi
    Jiang, Hualiang
    Liu, Hong
    ORGANIC LETTERS, 2008, 10 (20) : 4513 - 4516
  • [3] Efficient copper-catalyzed N-arylation of sulfoximines with aryl iodides and aryl bromides
    Sedelmeier, J
    Bolm, C
    JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (17): : 6904 - 6906
  • [4] Mild copper-catalyzed N-arylation of azaheterocycles with aryl halides
    Kuil, M
    Bekedam, EK
    Visser, GM
    van den Hoogenband, A
    Terpstra, JW
    Kamer, PCJ
    van Leeuwen, PWNM
    van Strijdonck, GPF
    TETRAHEDRON LETTERS, 2005, 46 (14) : 2405 - 2409
  • [5] Mild Copper-TBAF-Catalyzed N-Arylation of Sulfoximines with Aryl Siloxanes
    Kim, Jaeeun
    Ok, Jinpyo
    Kim, Sanghyuck
    Choi, Wonseok
    Lee, Phil Ho
    ORGANIC LETTERS, 2014, 16 (17) : 4602 - 4605
  • [6] Copper-catalyzed N-arylation of 2-arylindoles with aryl halides
    Liu, Wei
    Han, Li-Ya
    Liu, Rui-Li
    Xu, Li-Ge
    Bi, Yan-Lan
    CHINESE CHEMICAL LETTERS, 2014, 25 (09) : 1240 - 1243
  • [7] Copper-catalyzed N-arylation of 2-arylindoles with aryl halides
    Wei Liu
    Li-Ya Han
    Rui-Li Liu
    Li-Ge Xu
    Yan-Lan Bi
    Chinese Chemical Letters, 2014, 25 (09) : 1240 - 1243
  • [8] Efficient Copper-Catalyzed N-Arylation of Amides and Imidazoles with Aryl Iodides
    Ali, Md. Ashif
    Saha, Prasenjit
    Punniyamurthy, Tharmalingam
    SYNTHESIS-STUTTGART, 2010, (06): : 908 - 910
  • [9] Copper-Catalyzed N-Arylation of 2-Imidazolines with Aryl Iodides
    Davis, Owen A.
    Hughes, Matthew
    Bull, James A.
    JOURNAL OF ORGANIC CHEMISTRY, 2013, 78 (07): : 3470 - 3475
  • [10] Copper-catalyzed N-arylation of sulfonamides with aryl bromides and iodides using microwave heating
    He, H
    Wu, YJ
    TETRAHEDRON LETTERS, 2003, 44 (16) : 3385 - 3386
12345