Hydrothermal assembly of a new hydrogen-bonded network featuring bicapped dimerized [Si2Mo24O80(VO)4]8- polyanion

被引：12

作者：

Shi, ZY ^{[1
]}

Gu, XJ ^{[1
]}

Peng, J ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 10期

关键词：

bicapped keggin dimer; polyoxometalate; hydrothermal synthesis; electrochemical property;

D O I：

10.1016/j.inoche.2005.06.027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new hydrogen-bonded network featuring bicapped dimerized polyanion, (H(2)bpy)(4)[(Si2Mo16Mo8O80)-Mo-VI-O-v((VO)-O-IV)(4)] center dot 2H(2)O (1) (bpy = 4,4'-bipyridine), has been synthesized under hydrothermal conditions. The study of electrochemical property of compound I shows it undergoes three two-electron redox processes. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：886 / 889

页数：4

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