A self-complexing and self-assembling pillar[5]arene

被引:186
作者
Strutt, Nathan L. [1 ,2 ,3 ]
Zhang, Huacheng [1 ]
Giesener, Marc A. [1 ]
Lei, Juying [1 ]
Stoddart, J. Fraser [1 ,2 ,3 ]
机构
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[2] Korea Adv Inst Sci & Technol, NanoCentury KAIST Inst, Taejon 305701, South Korea
[3] Korea Adv Inst Sci & Technol, Grad Sch EEWS WCU, Taejon 305701, South Korea
基金
美国国家科学基金会;
关键词
SUPRAMOLECULAR POLYMERS; GUEST; HOST; COMPLEXATION; CONSTRUCTION; CYCLODEXTRIN; CUCURBITURIL; MOLECULES; UNITS;
D O I
10.1039/c2cc16030g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A monofunctionalised pillar[5]arene derivative carrying a viologen side chain which exhibits self-complexation in dilute dichloromethane solutions forms supramolecular daisy chain polymers and eventually organogels as its concentration is increased three-fold over the range from 0.1 to 100 mM.
引用
收藏
页码:1647 / 1649
页数:3
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