Well-Defined Soluble P3--Containing Rare-Earth-Metal Compounds

被引：44

作者：

Lv, Yingdong ^{[1
]}

Xu, Xin ^{[1
]}

Chen, Yaofeng ^{[1
]}

Leng, Xuebing ^{[1
]}

Borzov, Maxim V. ^{[2
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

[2] NW Univ Xian, Coll Chem & Mat Sci, Xian 710069, Shaanxi Prov, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 47期

基金：

中国国家自然科学基金;

关键词：

coordination modes; helical structures; phosphorus; rare-earth metals; solid-state structures; TERTIARY PHOSPHINE COMPLEXES; F-BLOCK METALS; CRYSTAL-STRUCTURE; LANTHANIDES; REACTIVITY; YTTRIUM;

D O I：

10.1002/anie.201105378

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rare find: Soluble P3--containing rare-earth-metal coordination compounds have been synthesized. A P3--containing polymetallic yttrium iodide was obtained through P-Si (or H) and P-C bond cleavage, and this compound can be transferred into other P3-- containing yttrium coordination compounds by metathesis reactions. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11227 / 11229

页数：3

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