Boosting reversible oxygen electrocatalysis with enhanced interfacial pyridinic-N-Co bonding in cobalt oxide/mesoporous N-doped graphene hybrids

被引:24
作者
Feng, Ting [1 ]
Zhao, Xue-Ru [1 ]
Dong, Cun-Ku [1 ]
Liu, Hui [1 ]
Du, Xi-Wen [1 ]
Yang, Jing [1 ]
机构
[1] Tianjin Univ, Inst New Energy Mat, Sch Mat Sci & Engn, Key Lab Adv Ceram & Machining Technol,Minist Educ, Tianjin 300072, Peoples R China
基金
中国国家自然科学基金;
关键词
REDUCTION; EVOLUTION; NITROGEN; CATALYSTS; OXIDE; NANOCRYSTALS; ELECTRODE; LEVEL;
D O I
10.1039/c8nr07945e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A hybrid electrocatalyst CoO/r-NLG with a high density of pyridinic-N-Co bonds was synthesized via pyrolysis treatments of a mixture of cobalt iron precursors and laser-induced mesoporous N-doped graphene, which achieved superb reversible ORR/OER activities, offering a low efficiency loss (E) of 0.635 V in a 1.0 M KOH electrolyte.
引用
收藏
页码:22140 / 22147
页数:8
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