Metal-promoted hydrolysis of bis(p-nitrophenyl)phosphate by trivalent manganese complexes with Schiff base ligands in Gemini micellar solution

被引：45

作者：

Jiang, Weidong ^{[1
,2
]}

Xu, Bin ^{[2
]}

Lin, Qi ^{[1
]}

Li, Jianzhang ^{[2
]}

Liu, Fuan ^{[2
]}

Zeng, Xiancheng ^{[1
]}

Chen, Hua ^{[1
]}

机构：

[1] Sichuan Univ, Otganomet Homogeneous Catalyt Inst, Chengdu 610064, Peoples R China

[2] Sichuan Univ Sci & Technol, Dept Chem, Key Lab Green Chem & Technol, Sichuan Zigong 643000, Peoples R China

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2008年 / 315卷 / 1-3期

基金：

中国国家自然科学基金;

关键词：

BNPP hydrolysis; kinetics; micelles; gemini surfactant; crowned Schiff base complexes;

D O I：

10.1016/j.colsurfa.2007.07.018

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two crowned Schiff base manganese(III) complexes (MnL2Cl, L = L-1, L-2) were used to catalyze the hydrolysis of bis(p-nitrophenyl)phosphate (BNPP) in Gemini surfactants [bis(hexadecyidimethylammonium)hexane bromide (abbreviation 16-6-16, 2Br(-))] solution. In comparison with the rate of BNPP spontaneous hydrolysis, a six orders of magnitude in rate enhancement was observed in (MnL2Cl)-Cl-1/16-6-16 and (MnL2Cl)-Cl-2/16-6-16 systems. Owing to the different structure, (MnL2Cl)-Cl-2 shows better activity than (MnL2Cl)-Cl-1. Especially, the effects of three different micelles, i.e., 16-6-16 micelles, CTAB (hexadecyltrimethylammonium bromide) micelles, LSS (n-lauroooylsarcosine sodium) micelles, on the hydrolysis of BNPP catalyzed by (MnL2Cl)-Cl-2 were evaluated at pH7.50. Experimental observations clearly demonstrate that Gemini 16-6-16 micelle is the best one for BNPP hydrolysis among three kinds of micellar media. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：103 / 109

页数：7

共 47 条

[1] COPOLYMERIZATION OF ACRYLAMIDE AND A HYDROPHOBIC MONOMER IN AN AQUEOUS MICELLAR MEDIUM - EFFECT OF THE SURFACTANT ON THE COPOLYMER MICROSTRUCTURE [J].

BIGGS, S ;

HILL, A ;

SELB, J ;

CANDAU, F .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (03) :1505-1511

[2] BIOMIMETIC CHEMISTRY AND ARTIFICIAL ENZYMES - CATALYSIS BY DESIGN [J].

BRESLOW, R .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (03) :146-153

[3] MICELLAR EFFECTS UPON HYDROLYSIS OF BIS-2,4-DINITROPHENYL PHOSPHATE [J].

BUIST, GJ ;

BUNTON, CA ;

ROBINSON, L ;

SEPULVED.L ;

STAM, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (13) :4072-&

[4] Hydrolysis of phosphodiester catalyzed by analogous dinuclear Cu(II) complex in CTAB micellar solution [J].

Cheng Si-Qing ;

Wang You-Rong ;

Yan Jian-Fang ;

Zeng Xiancheng .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2007, 292 (01) :32-35

[5] CO(III) COMPLEX PROMOTED HYDROLYSIS OF PHOSPHATE DIESTERS - COMPARISON IN REACTIVITY OF RIGID CIS-DIAQUOTETRAAZACOBALT(III) COMPLEXES [J].

CHIN, J ;

BANASZCZYK, M ;

JUBIAN, V ;

ZOU, X .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (01) :186-190

[6] Artificial dinuclear phosphoesterases [J].

Chin, J .

CURRENT OPINION IN CHEMICAL BIOLOGY, 1997, 1 (04) :514-521

[7] DEVELOPING ARTIFICIAL HYDROLYTIC METALLOENZYMES BY A UNIFIED MECHANISTIC APPROACH [J].

CHIN, J .

ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (05) :145-152

[8] Catalysis of phosphate triester hydrolysis by micelles of hexadecyltrimethylammonium anti-pyruvaldehyde 1-oximate [J].

Couderc, S ;

Toullec, J .

LANGMUIR, 2001, 17 (13) :3819-3828

[9] Chemical nucleases [J].

Cowan, JA .

CURRENT OPINION IN CHEMICAL BIOLOGY, 2001, 5 (06) :634-642

[10] Metallomicellar catalysis: Hydrolysis of phosphodiester with Cu(II) and Zn(II) complexes in micellar solution [J].

Du, J ;

Chen, MZ ;

Wu, YR ;

Zeng, XC ;

Liu, YJ ;

Shunzo, Y ;

Yoshimi, S .

JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2003, 24 (05) :683-689

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