Investigation of the Photoluminescence Properties and Nonlinear Optical Responses of Thermochemically Synthesized CdS Nanoparticles

被引:1
作者
Molaei, M. [1 ]
Saievar-Iranizad, E. [1 ]
Dehghani, Z. [1 ]
Taghavinia, N. [1 ]
Majlesara, M. H. [1 ]
机构
[1] Tarbiat Modares Univ, Fac Sci, Dept Phys, Tehran, Iran
关键词
nonlinear optical properties; z-scan technique; SILVER NANOPARTICLES; CLUSTERS; FLUORESCENCE;
D O I
10.1080/15533174.2010.522673
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In this work, we have investigated the nonlinear optical properties of thermochemically synthesized CdS nanoparticles, The structure and optical property of the nanopartilces were characterized by means of XRD, UV-visible optical spectroscopy, and photoluminescence (PL) and Z-scan technique was used to measure the nonlinear refraction and absorption indexes. X-ray diffraction (XRD) analysis demonstrated hexagonal phase CdS nanoparticles with an average size around 1.8 nm. Band gap of nanocrystals was about 3.2 eV and they showed a broad band emission from 400-750 nm centered at 504 nm. The nonlinear refractive index was about in order of 10-8 (cm2/W), and the nonlinear absorption coefficient was obtained in order of 10-3 (cm/W) with negative sign. The linear absorption coefficient ( was obtained about 2.62 cm-1.
引用
收藏
页码:224 / 227
页数:4
相关论文
共 15 条
[1]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[2]   Non-linear optical properties of silver nanoparticles prepared by hydrogen reduction method [J].
Ara, M. H. Majles ;
Dehghani, Z. ;
Sahraei, R. ;
Nabiyouni, G. .
OPTICS COMMUNICATIONS, 2010, 283 (08) :1650-1653
[3]   Characterisation and nonlinear optical properties of CdS nano-particles [J].
Ara, M. H. Majles ;
Dehghani, Z. ;
Iranizad, E. Saievar .
INTERNATIONAL JOURNAL OF NANOTECHNOLOGY, 2009, 6 (10-11) :1006-1014
[4]   Self-assembly and photoluminescence of CdS-mercaptoacetic clusters with internal structures [J].
Chen, HM ;
Huang, XF ;
Xu, L ;
Xu, J ;
Chen, KJ ;
Feng, D .
SUPERLATTICES AND MICROSTRUCTURES, 2000, 27 (01) :1-5
[5]   Formation, structure and fluorescence of CdS clusters in a mesoporous zeolite [J].
Chen, W ;
Xu, Y ;
Lin, ZJ ;
Wang, ZG ;
Lin, LY .
SOLID STATE COMMUNICATIONS, 1998, 105 (02) :129-134
[6]   Structure and photophysics of semiconductor nanocrystals [J].
Eychmüller, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (28) :6514-6528
[7]   pH effects on the second-order nonlinear optical properties of surface modified US nanoparticles [J].
Fu, DG ;
Zhang, Y ;
Liu, JZ ;
Lu, ZH .
MATERIALS CHEMISTRY AND PHYSICS, 2003, 77 (01) :285-288
[8]   Study on the non-linear refraction of silver nanoparticles with aggregation effect [J].
Gang, W ;
Zhang, Y ;
Cui, YP ;
Duan, MY ;
Liu, M .
OPTICS COMMUNICATIONS, 2005, 249 (1-3) :311-317
[9]   Z-scan determination of the third-order optical nonlinearity of a triphenylmethane dye using 633 nm He-Ne laser [J].
Geethakrishnan, T. ;
Palanisamy, P. K. .
OPTICS COMMUNICATIONS, 2007, 270 (02) :424-428
[10]   DETECTION OF SHALLOW ELECTRON TRAPS IN QUANTUM SIZED CDS BY FLUORESCENCE QUENCHING EXPERIMENTS [J].
HASSELBARTH, A ;
EYCHMULLER, A ;
WELLER, H .
CHEMICAL PHYSICS LETTERS, 1993, 203 (2-3) :271-276