A Facile Synthesis and Thermal Stability of cis-[Pd(NH3)2(C2O4)]

被引：0

作者：

Xia, Wenzheng ^{[1
]}

Pan, Zaifu ^{[1
]}

Chen, Jialin ^{[1
]}

Ye, Qingsong ^{[1
]}

Liu, Weiping ^{[1
]}

机构：

[1] Kunming Inst Precious Met, State Key Lab Adv Technol Platinum Met, Kunming 650106, Peoples R China

来源：

ASIAN JOURNAL OF CHEMISTRY | 2011年 / 23卷 / 02期

关键词：

Diammineoxalatopalladium; Synthesis; Characterization; Thermal decomposition behaviour; COMPLEXES;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple and facile method for synthesis of cis-[Pd(NH3)(2)(C2O4)] has been developed and the thermal decomposition behaviour investigated I with TG-DTA under air and nitrogen atmosphere. The complex was prepared by the direct reaction of palladium chloride with ammonium oxalate at mild temperature and the yield was up to 76 %. cis-[Pd(NH3)(2)(C2O4)] undergoes the thermal decomposition, respectively, at 180 degrees C in air and 172 degrees C in N-2, leading to the formation of Pd powder and CO2 and NH3 as the gas products.

引用

页码：785 / 787

页数：3

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