A Facile Synthesis and Thermal Stability of cis-[Pd(NH3)2(C2O4)]

被引：0
|
作者：
Xia, Wenzheng [1 ]
Pan, Zaifu [1 ]
Chen, Jialin [1 ]
Ye, Qingsong [1 ]
Liu, Weiping [1 ]
机构：
[1] Kunming Inst Precious Met, State Key Lab Adv Technol Platinum Met, Kunming 650106, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2011年 / 23卷 / 02期
关键词：
Diammineoxalatopalladium; Synthesis; Characterization; Thermal decomposition behaviour; COMPLEXES;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple and facile method for synthesis of cis-[Pd(NH3)(2)(C2O4)] has been developed and the thermal decomposition behaviour investigated I with TG-DTA under air and nitrogen atmosphere. The complex was prepared by the direct reaction of palladium chloride with ammonium oxalate at mild temperature and the yield was up to 76 %. cis-[Pd(NH3)(2)(C2O4)] undergoes the thermal decomposition, respectively, at 180 degrees C in air and 172 degrees C in N-2, leading to the formation of Pd powder and CO2 and NH3 as the gas products.
引用
收藏
页码：785 / 787
页数：3
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