Rational synthesis of a novel 3,3,5-c polyhedral metal-organic framework with high thermal stability and hydrogen storage capability

被引：115

作者：

Liu, Jianqiang ^{[1
]}

Liu, Guoliang ^{[2
,3
]}

Gu, Chuying ^{[1
]}

Liu, Weicong ^{[1
]}

Xu, Jingwen ^{[1
]}

Li, Baohong ^{[1
]}

Wang, Wenjing ^{[2
,3
]}

机构：

[1] Guangdong Med Univ, Sch Pharm, Dongguan 523808, Peoples R China

[2] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China

[3] Univ Chinese Acad Sci, Beijing, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2016年 / 4卷 / 30期

基金：

中国国家自然科学基金;

关键词：

ISORETICULAR SERIES; HIGH H-2; CU-24(ISOPHTHALATE)(24) CUBOCTAHEDRA; IMIDAZOLATE FRAMEWORKS; ADSORPTION CAPACITY; POROUS MATERIALS; BUILDING-BLOCKS; SURFACE-AREA; CO2; SORPTION;

D O I：

10.1039/c6ta03675a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

By using a functionalized ligand strategy, a novel (3,3,5)-c polyhedron-based metal-organic framework (GDMU-2) with high thermal stability has been constructed. GDMU-2 shows a high H-2 uptake of 240.7 cm(3) g(-1) (2.16 wt%) at 77 K and 1 bar, and also exhibits a good selective adsorption of CO2 over N-2 and CH4.

引用

页码：11630 / 11634

页数：5

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