Flow-induced alignment of lamellar block copolymer melts

被引:96
作者
Chen, ZR [1 ]
Kornfield, JA [1 ]
机构
[1] CALTECH, Pasadena, CA 91125 USA
关键词
SAXS; SANS; TEM;
D O I
10.1016/S0032-3861(98)00136-0
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Toward the integrated synthesis and processing of functional block copolymer nanostructures, the physics of flow-induced alignment of block copolymers must be understood to predict the direction, rate and degree of alignment. In this review we focus on key issues regarding flow-induced alignment of lamellae. A three-dimensional mapping summarizes previous results on the selection of alignment directions (parallel or perpendicular) and their pathways in terms of three dimensionless parameters: frequency, temperature and strain amplitude. Trajectories, kinetics and structural evolution are explored in a fourth dimension (time). The challenge of developing adequate experimental methods for monitoring transient structure is discussed. A comprehensive experimental approach, which combines in-situ rheo-optical measurements and ex-situ structural characterization by electron microscopy and X-ray scattering, is presented as a new tool for tracking changes of microstructure and orientation during flow-induced alignment. Various mechanisms that have been proposed over the past two decades are reviewed and re-evaluated based on recent experimental results. Outstanding questions and new issues raised by ABC triblock copolymer nanstructures are discussed. (C) 1998 Elsevier Science Ltd. All rights reserved.
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页码:4679 / 4699
页数:21
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