Effect of MnO2 on the Piezoelectric Properties of the 0.75Pb(Zr0.47Ti0.53)O3-0.25Pb(Zn1/3Nb2/3)O3 Ceramics

被引:53
作者
Park, Hwi-Yeol [1 ]
Nam, Chan-Hee [1 ]
Seo, In-Tae [1 ]
Choi, Jae-Hong [1 ]
Nahm, Sahn [1 ]
Lee, Hyeung-Gyu [2 ]
Kim, Kwang-Jin [3 ]
Jeong, Seong-Min [3 ]
机构
[1] Korea Univ, Dept Mat Sci & Engn, Seoul 136701, South Korea
[2] Korea Elect Technol Inst, Gyeonggi Do 463816, South Korea
[3] Korea Inst Ceram Engn & Technol, Seoul 153801, South Korea
关键词
TEMPERATURE; TRANSFORMER; FABRICATION; FREQUENCY;
D O I
10.1111/j.1551-2916.2010.03888.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
MnO2 was added to 0.75Pb(Zr0.47Ti0.53)O-3-0.25Pb(Zn1/3Nb2/3)O-3 (0.75PZT-0.25PZN) ceramics in order to make a high-power piezoelectric material. The Mn4+ ion produced a defect dipole consisting of an Mn4+ ion and an oxygen vacancy that transformed the 0.75PZT-0.25PZN ceramics into hard materials. The Q(m) value significantly increased with the addition of MnO2 and reached a value of 1680 for the 1.5 mol% MnO2-added 0.75PZT-0.25PZN ceramic. Moreover, this specimen exhibited a high k(p) of 0.53 with a epsilon T-3/epsilon(0) of 1518. Additionally, the 1.5 mol% MnO2-added 0.75PZT-0.25PZN ceramics sintered at 900 degrees C for 4 h also exhibited high piezoelectric properties of Q(m)=1115, k(p)=0.50, and epsilon T-3/epsilon(0)=1537.
引用
收藏
页码:2537 / 2540
页数:4
相关论文
共 26 条
[1]   Low temperature sintering and piezoelectric properties in Pb(ZrxTi1-x)O3-Pb(Zn1/3Nb2/3)O3-Pb(Ni1/3Nb2/3)O3 ceramics [J].
Ahn, CW ;
Song, HC ;
Park, SH ;
Nahm, S ;
Uchino, K ;
Priya, S ;
Lee, HG ;
Kang, NK .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2005, 44 (03) :1314-1321
[2]   Effects of Zr/Ti ratio on structural, dielectric and piezoelectric properties of Mn- and (Mn, F)-doped lead zirconate titanate ceramics [J].
Boucher, Eric ;
Guiffard, Benoit ;
Lebrun, Laurent ;
Guyomar, Daniel .
CERAMICS INTERNATIONAL, 2006, 32 (05) :479-485
[3]   Fabrication and characterization of low temperature sintering PMN-PZN-PZT step-down multilayer piezoelectric transformer [J].
Chao, Xiaolian ;
Yang, Zupei ;
Li, Gang ;
Cheng, Yaoqiang .
SENSORS AND ACTUATORS A-PHYSICAL, 2008, 144 (01) :117-123
[4]   Microstructural, dielectric and piezoelectric properties of low-temperature sintering -: Pb(Co1/2W1/2)O3-Pb(Mn1/2Nb2/3)O3-Pb(Zr,Ti)O3 ceramics with the addition of Li2CO3 and Bi2O3 [J].
Chung, K ;
Yoo, J ;
Lee, C ;
Lee, D ;
Jeong, Y ;
Lee, H .
SENSORS AND ACTUATORS A-PHYSICAL, 2006, 125 (02) :340-345
[5]  
Crumm AT, 1998, J AM CERAM SOC, V81, P1053, DOI 10.1111/j.1151-2916.1998.tb02448.x
[6]   Eu and Yb substituent effects on the properties of Pb(Zr0.52Ti0.48)O3-Pb(Mn1/3Sb2/3)O3 ceramics:: Development of a new high-power piezoelectric with enhanced vibrational velocity [J].
Gao, YK ;
Chen, EH ;
Ryu, J ;
Uchino, K ;
Viehland, D .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2001, 40 (2A) :687-693
[7]   Ferroelectric ceramics: History and technology [J].
Haertling, GH .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1999, 82 (04) :797-818
[8]   Low-temperature sintering and properties of (Pb, Ba, Sr)(Zr, Ti, Sb)O3 piezoelectric ceramics using sintering aids [J].
Hayashi, T ;
Inoue, T ;
Akiyama, Y .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1999, 38 (9B) :5549-5552
[9]   Effects of addition of MnO on piezoelectric properties of lead zirconate titanate [J].
He, LX ;
Li, CE .
JOURNAL OF MATERIALS SCIENCE, 2000, 35 (10) :2477-2480
[10]   INTRINSIC NONSTOICHIOMETRY IN LEAD ZIRCONATE LEAD TITANATE SYSTEM DETERMINED BY KNUDSEN EFFUSION [J].
HOLMAN, RL ;
FULRATH, RM .
JOURNAL OF APPLIED PHYSICS, 1973, 44 (12) :5227-5236