Synthesis, Structure and Properties of an Organically Templated Molybdate Zn2(bpe)Mo2O8 (bpe=1,2-Bis(4-pyridyl)ethane)

被引：1

作者：

Wang, Wen-Ju ^{[1
]}

Zhang, Zhe-Yu ^{[1
]}

Mei, Ze-Min ^{[1
]}

Li, Feng-Yan ^{[2
]}

机构：

[1] Baicheng Teachers Coll, Dept Chem, Baicheng 137000, Jilin, Peoples R China

[2] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China

来源：

JOURNAL OF CLUSTER SCIENCE | 2016年 / 27卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Metal-oxide organic framework; Molybdenum oxides; Crystal structure; SERIES;

D O I：

10.1007/s10876-015-0943-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new organically templated molybdenum oxides compound Zn-2(bpe)Mo2O8 (bpe = 1,2-bis(4-pyridyl)ethane) has been hydrothermal synthesized and characterized by single X-ray analysis, element analysis, IR spectroscopy, TG analysis, diffuse reflectance UV-Vis spectra. Compound 1 shows a three-dimensional net-like structure, where the bimetallic oxide layers {ZnMoO4} were knitted together with the bpe ligands. The optical band gap for 1 was 2.5 eV, which is comparable to that of TiO2. Moreover, the photoluminescent properties of 1 have been investigated at room temperature.

引用

页码：617 / 624

页数：8

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