Ring closing metathesis reactions on a phosphonate template

被引：64

作者：

Hanson, PR ^{[1
]}

Stoianova, DS ^{[1
]}

机构：

[1] Univ Kansas, Dept Chem, Lawrence, KS 66045 USA

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 23期

关键词：

D O I：

10.1016/S0040-4039(98)00728-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first examples of ring-closing metathesis reactions on a phosphonate template catalyzed by the ruthenium alkylidene 3 are described. The yield, rate, and mode of cyclization in these reactions are sensitive to simple olefin substitution. The highlight of this method is the efficient syntheses of 2-alkyloxy-3,6-dihydro-[1,2]oxaphosphinine 2-oxide heterocycles (2). (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3939 / 3942

页数：4

共 47 条

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