Recognition-mediated cucurbit[7]uril-heptamolybdate hybrid material: a facile supramolecular strategy for 99mTc separation

被引:36
作者
Goel, Teena [1 ,3 ]
Barooah, Nilotpal [1 ]
Mallia, Madhava B. [2 ]
Bhasikuttan, Achikanath C. [1 ]
Mohanty, Jyotirmayee [1 ]
机构
[1] Bhabha Atom Res Ctr, Radiat & Photochem Div, Bombay 400085, Maharashtra, India
[2] Bhabha Atom Res Ctr, Radiopharmaceut Chem Sect, Bombay 400085, Maharashtra, India
[3] Board Radiat & Isotope Technol, Reg Ctr, Delhi 110054, India
关键词
CHEMISTRY; CUCURBITURIL; ARCHITECTURES;
D O I
10.1039/c6cc02613c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the construction of a novel non-covalently held cucurbit[7]uril-heptamolybdate hybrid material for the first time, and demonstrate its application as a generator bed for the facile and efficient separation of the Tc-99m radiotracer, which is in demand for several theranostic applications.
引用
收藏
页码:7306 / 7309
页数:4
相关论文
共 33 条
[1]   Cucurbiturils: from synthesis to high-affinity binding and catalysis [J].
Assaf, Khaleel I. ;
Nau, Werner M. .
CHEMICAL SOCIETY REVIEWS, 2015, 44 (02) :394-418
[2]   Non-covalent interactions of coumarin dyes with cucurbit[7]uril macrocycle: modulation of ICT to TICT state conversion [J].
Barooah, Nilotpal ;
Mohanty, Jyotirmayee ;
Pal, Haridas ;
Bhasikuttan, Achikanath C. .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2012, 10 (26) :5055-5062
[3]   Cucurbituril-Based Molecular Recognition [J].
Barrow, Steven J. ;
Kasera, Setu ;
Rowland, Matthew J. ;
del Barrio, Jesus ;
Scherman, Oren A. .
CHEMICAL REVIEWS, 2015, 115 (22) :12320-12406
[4]   Cucurbit[n]uril based supramolecular assemblies: tunable physico-chemical properties and their prospects [J].
Bhasikuttan, Achikanath C. ;
Pal, Haridas ;
Mohanty, Jyotirmayee .
CHEMICAL COMMUNICATIONS, 2011, 47 (36) :9959-9971
[5]   A novel electrochemical 99Mo/99mTc generator [J].
Chakravarty, Rubel ;
Venkatesh, Meera ;
Dash, Ashutosh .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2011, 290 (01) :45-51
[6]   Cucurbit[6]uril-Based Supramolecular Assemblies: Possible Application in Radioactive Cesium Cation Capture [J].
Chen, Kai ;
Kong, Yan-Shang ;
Zhao, Yue ;
Yang, Ji-Min ;
Lu, Yi ;
Sun, Wei-Yin .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (48) :16744-16747
[7]   Cooperative Metal Ion Binding to a Cucurbit[7]uril-Thioflavin T Complex: Demonstration of a Stimulus-Responsive Fluorescent Supramolecular Capsule [J].
Choudhury, Sharmistha Dutta ;
Mohanty, Jyotirmayee ;
Pal, Haridas ;
Bhasikuttan, Achikanath C. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (04) :1395-1401
[8]   Photophysical Studies on the Noncovalent Interaction of Thioflavin T with Cucurbit[n]uril Macrocycles [J].
Choudhury, Sharmistha Dutta ;
Mohanty, Jyotirmayee ;
Upadhyaya, Hari P. ;
Bhasikuttan, Achikanath C. ;
Pal, Haridas .
JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (07) :1891-1898
[9]   Directed Assembly of Inorganic Polyoxometalate-based Micrometer-Scale Tubular Architectures by Using Optical Control [J].
Cooper, Geoffrey J. T. ;
Bowman, Richard W. ;
Magennis, E. Peter ;
Fernandez-Trillo, Francisco ;
Alexander, Cameron ;
Padgett, Miles J. ;
Cronin, Leroy .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (51) :12754-12758
[10]   The chemistry and biochemistry of vanadium and the biological activities exerted by vanadium compounds [J].
Crans, DC ;
Smee, JJ ;
Gaidamauskas, E ;
Yang, LQ .
CHEMICAL REVIEWS, 2004, 104 (02) :849-902