Silver-assisted electroless etching mechanism of silicon

被引:30
作者
Douani, R. [2 ]
Si-Larbi, K. [1 ]
Hadjersi, T. [1 ]
Megouda, N. [2 ]
Manseri, A. [1 ]
机构
[1] UDTS, Algiers, Algeria
[2] Univ Mouloud Mammeri, Fac Sci, Tizi Ouzou, Algeria
来源
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 2008年 / 205卷 / 02期
关键词
D O I
10.1002/pssa.200723159
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The morphology of metal-assisted electroless etched n-type silicon in HF-oxidizing agent-H2O etching system as a function of oxidizingtype and etching time was studied. Three types of oxidizing agent were investagated: Na2S2O8, K2Cr2O7 and KMnO4. The layers formed on silicon were investigated by scanning electron microscopy and energy-dispersive X-ray analysis. It is shown that the morphology of the etched layers depends strongly on the type of oxidizing agent. The secondary ion mass spectra of the etched layers reveal that the deposited silver diffuses into the etched layers during etching. Finally, a discussion on the dissolution mechanism of silicon by silver-assisted electroless etching presented. (C) 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:225 / 230
页数:6
相关论文
共 16 条
[1]   In-plane control of morphology and tunable photoluminescence in porous silicon produced by metal-assisted electroless chemical etching [J].
Chattopadhyay, S ;
Li, XL ;
Bohn, PW .
JOURNAL OF APPLIED PHYSICS, 2002, 91 (09) :6134-6140
[2]   Fabrication and optimization of porous silicon substrates for diffusion membrane applications [J].
Cruz, S ;
Hönig-dOrville, A ;
Müller, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (06) :C418-C424
[3]   Preparation of thin porous silicon layers by stain etching [J].
DimovaMalinovska, D ;
SendovaVassileva, M ;
Tzenov, N ;
Kamenova, M .
THIN SOLID FILMS, 1997, 297 (1-2) :9-12
[4]   Electrochemical characterization of the open-circuit deposition of platinum on silicon from fluoride solutions [J].
Gorostiza, P ;
Allongue, P ;
Díaz, R ;
Morante, JR ;
Sanz, F .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (26) :6454-6461
[5]   Photoluminescence from undoped silicon after chemical etching combined with metal plating [J].
Hadjersi, T ;
Gabouze, N ;
Yamamoto, N ;
Sakamaki, K ;
Takai, H ;
Ababou, A ;
Kooij, ES .
Physica Status Solidi C - Conferences and Critical Reviews, Vol 2, No 9, 2005, 2 (09) :3384-3388
[6]   Catalytic amplification of the soft lithographic patterning of Si. Nonelectrochemical orthogonal fabrication of photoluminescent porous Si pixel arrays [J].
Harada, Y ;
Li, XL ;
Bohn, PW ;
Nuzzo, RG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (36) :8709-8717
[7]   VISIBLE PHOTOLUMINESCENCE FROM OXIDIZED SI NANOMETER-SIZED SPHERES - EXCITON CONFINEMENT ON A SPHERICAL-SHELL [J].
KANEMITSU, Y ;
OGAWA, T ;
SHIRAISHI, K ;
TAKEDA, K .
PHYSICAL REVIEW B, 1993, 48 (07) :4883-4886
[8]   POROUS SILICON FORMATION - A QUANTUM WIRE EFFECT [J].
LEHMANN, V ;
GOSELE, U .
APPLIED PHYSICS LETTERS, 1991, 58 (08) :856-858
[9]   Metal-assisted chemical etching in HF/H2O2 produces porous silicon [J].
Li, X ;
Bohn, PW .
APPLIED PHYSICS LETTERS, 2000, 77 (16) :2572-2574
[10]  
Lide DV., 1995, CRC HDB CHEM PHYS