Energetic Materials with Promising Properties: Synthesis and Characterization of 4,4-Bis(5-nitro-1,2,3-2H-triazole) Derivatives

被引：90

作者：

He, Chunlin ^{[1
]}

Shreeve, Jean'ne M. ^{[1
]}

机构：

[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 21期

基金：

美国国家科学基金会;

关键词：

amination; bis(1,2 3-triazole); detonation properties; energetic materials; AMINATION; DESIGN;

D O I：

10.1002/anie.201412303

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using a variety of functionalization strategies, derivatives of 4, 4-bis(5-nitro-1,2,3-2H-triazole) were designed, synthesized, and characterized. The isomers were separated, their structures were confirmed with single-crystal X-ray analysis, and their properties were determined by differential scanning calorimetry, density, impact sensitivity, heat of formation, and detonation velocity and pressure (calculated by EXPLO5 V6.01). Those materials were found to exhibit superior detonation performance when compared with the other fully carbon-nitrated bis(azoles).

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收藏

页码：6260 / 6264

页数：5

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