Polymorphism in bis(4-dimethylamino-pyridinium)tetrachlorocuprate(II)

被引：51

作者：

Haddad, S

Willett, RD ^{[1
]}

机构：

[1] Washington State Univ, Dept Chem, Pullman, WA 99164 USA

[2] Univ Jordan, Dept Chem, Amman, Jordan

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 10期

关键词：

D O I：

10.1021/ic000613c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound crystallizes in both a yellow and a green phase. The pyridinium cations form bifurcated hydrogen bonds to the CuCl42- anions to form molecular species. The packing of these molecular species force the CuCl42- chromophore to be distorted more toward a square planar geometry in the green phase. The packing in both phases appears to be strongly influenced by C-H...CI electrostatic interactions. [GRAPHICS]

引用

页码：2457 / +

页数：5

共 26 条

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