Electrolytes for solid-state lithium rechargeable batteries: recent advances and perspectives

被引:1399
作者
Quartarone, Eliana
Mustarelli, Piercarlo [1 ]
机构
[1] Univ Pavia, Dept Phys Chem, I-27100 Pavia, Italy
关键词
N-METHYLPYRROLIDINIUM BIS(TRIFLUOROMETHANESULFONYL)-IMIDE; POLYMER ELECTROLYTES; IONIC LIQUIDS; TRANSPORT-PROPERTIES; ELECTROCHEMICAL PROPERTIES; TRANSFERENCE NUMBERS; SOLVENT-FREE; PVDF-HFP; CONDUCTIVITY; LI;
D O I
10.1039/c0cs00081g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This critical review presents an overview of the various classes of Li+ conductors for use as electrolytes in lithium polymer batteries and all-solid state microbatteries. Initially, we recall the main models for ion transport and the structure-transport relationships at the basis of the observed conductivity behaviours. Emphasis is then placed on the physico-chemical and functional parameters relevant for optimal electrolytes preparation, as well as on the techniques of choice for their evaluation. Finally, the state of the art of polymer and ceramic electrolytes is reported, and the most interesting strategies for the future developments are described (121 references).
引用
收藏
页码:2525 / 2540
页数:16
相关论文
共 123 条
  • [1] Polyethylene oxide electrolyte membranes with pyrrolidinium-based ionic liquids
    Abitelli, E.
    Ferrari, S.
    Quartarone, E.
    Mustarelli, P.
    Magistris, A.
    Fagnoni, M.
    Albini, A.
    Gerbaldi, C.
    [J]. ELECTROCHIMICA ACTA, 2010, 55 (19) : 5478 - 5484
  • [2] Highly conductive PEO-like polymer electrolytes
    Abraham, KM
    Jiang, Z
    Carroll, B
    [J]. CHEMISTRY OF MATERIALS, 1997, 9 (09) : 1978 - 1988
  • [3] A polymer electrolyte-based rechargeable lithium/oxygen battery
    Abraham, KM
    Jiang, Z
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) : 1 - 5
  • [4] Solid polymer electrolytes: materials designing and all-solid-state battery applications: an overview
    Agrawal, R. C.
    Pandey, G. P.
    [J]. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2008, 41 (22)
  • [5] RUBBERY SOLID ELECTROLYTES WITH DOMINANT CATIONIC TRANSPORT AND HIGH AMBIENT CONDUCTIVITY
    ANGELL, CA
    LIU, C
    SANCHEZ, E
    [J]. NATURE, 1993, 362 (6416) : 137 - 139
  • [6] A new class of advanced polymer electrolytes and their relevance in plastic-like, rechargeable lithium batteries
    Appetecchi, GB
    Dautzenberg, G
    Scrosati, B
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) : 6 - 12
  • [7] Transport and interfacial properties of composite polymer electrolytes
    Appetecchi, GB
    Croce, F
    Persi, L
    Ronci, F
    Scrosati, B
    [J]. ELECTROCHIMICA ACTA, 2000, 45 (8-9) : 1481 - 1490
  • [8] PEO-based electrolyte membranes based on LiBC4O8 salt
    Appetecchi, GB
    Zane, D
    Scrosati, B
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (09) : A1369 - A1374
  • [9] Effect of the alkyl group on the synthesis and the electrochemical properties of N-alkyl-N-methyl-pyrrolidinium bis(trifluoromethanesulfonyl)imide ionic liquids
    Appetecchi, Giovanni B.
    Montanino, Maria
    Zane, Daniela
    Carewska, Maria
    Alessandrini, Fabrizio
    Passerini, Stefano
    [J]. ELECTROCHIMICA ACTA, 2009, 54 (04) : 1325 - 1332
  • [10] Nanostructured materials for advanced energy conversion and storage devices
    Aricò, AS
    Bruce, P
    Scrosati, B
    Tarascon, JM
    Van Schalkwijk, W
    [J]. NATURE MATERIALS, 2005, 4 (05) : 366 - 377