Molecular Dynamics of Flexible Polar Cations in a Variable Confined Space: Toward Exceptional Two-Step Nonlinear Optical Switches

被引：199
作者：
Xu, Wei-Jian [1 ]
He, Chun-Ting [1 ]
Ji, Cheng-Min [2 ]
Chen, Shao-Li [1 ]
Huang, Rui-Kang [1 ]
Lin, Rui-Biao [1 ]
Xue, Wei [1 ]
Luo, Jun-Hua [2 ]
Zhang, Wei-Xiong [1 ]
Chen, Xiao-Ming [1 ]
机构：
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Peoples R China
来源：
ADVANCED MATERIALS | 2016年 / 28卷 / 28期
关键词：
METAL-ORGANIC FRAMEWORK; ROOM-TEMPERATURE; PHASE-TRANSITION; PEROVSKITE-LIKE; COORDINATION POLYMERS; DIELECTRIC-CONSTANT; COMPOUND; FERROELECTRICITY; CRYSTAL; BISTABILITY;
D O I：
10.1002/adma.201600895
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The changeable molecular dynamics of flexible polar cations in the variable confined space between inorganic chains brings about a new type of two-step nonlinear optical (NLO) switch with genuine "off-on-off" second harmonic generation (SHG) conversion between one NLO-active state and two NLO-inactive states.
引用
收藏
页码：CP4 / CP4
页数：1
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