Partial molar volume of dodecyltrimethylammonium hydroxide in water and NaOH aqueous solutions

被引:12
|
作者
Morini, MA [1 ]
Minardi, RM [1 ]
Schulz, PC [1 ]
Puig, JE [1 ]
Rodriguez, JL [1 ]
机构
[1] Univ Guadalajara, Dept Ingn Quim, Guadalajara 44430, Jalisco, Mexico
关键词
hydroxide surfactants; micelles; partial molar volume dodecyltrimethylammonium hydroxide;
D O I
10.1007/s003960050304
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The partial molar volume of dodecyltrimethylammonium hydroxide in water and aqueous NaOH solutions was measured. The addition of NaOH did not affect either the micellized or the unmicellized molecules. The expansion on micellization is much larger than in dodecyltrimethylammonium bromide systems, which reflects the stronger ionization of the hydroxide surfactant micelles, when compared with that of the bromide amphiphile.
引用
收藏
页码:738 / 742
页数:5
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