Recyclable Catalysts for Palladium-Catalyzed C-O Coupling Reactions, Buchwald-Hartwig Aminations, and Sonogashira Reactions

被引：97
|
作者：
Dumrath, Andreas [1 ]
Wu, Xiao-Feng [1 ]
Neumann, Helfried [1 ]
Spannenberg, Anke [1 ]
Jackstell, Ralf [1 ]
Beller, Matthias [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse, D-18059 Rostock, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 47期
关键词：
catalyst recycling; hydroxylation; palladium; phosphanes; Sonogashira reaction; N-HETEROCYCLIC CARBENES; LIGAND-FREE PALLADIUM; SUZUKI-MIYAURA; ARYL HALIDES; REDUCTIVE ELIMINATION; CARBONYLATION REACTIONS; PHOSPHINE-LIGANDS; HECK REACTIONS; IONIC LIQUIDS; BOND;
D O I：
10.1002/anie.201001787
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Simply reuse: Homogeneous palladium catalysts are effective and attractive tools for advanced organic synthesis (see example). Compound 1 belongs to a new class of ligands that enable recycling of the precious-metal catalyst directly from the reaction without any heterogenization. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：8988 / 8992
页数：5
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