Recyclable Catalysts for Palladium-Catalyzed C-O Coupling Reactions, Buchwald-Hartwig Aminations, and Sonogashira Reactions

被引:97
作者
Dumrath, Andreas [1 ]
Wu, Xiao-Feng [1 ]
Neumann, Helfried [1 ]
Spannenberg, Anke [1 ]
Jackstell, Ralf [1 ]
Beller, Matthias [1 ]
机构
[1] Univ Rostock, Leibniz Inst Katalyse, D-18059 Rostock, Germany
关键词
catalyst recycling; hydroxylation; palladium; phosphanes; Sonogashira reaction; N-HETEROCYCLIC CARBENES; LIGAND-FREE PALLADIUM; SUZUKI-MIYAURA; ARYL HALIDES; REDUCTIVE ELIMINATION; CARBONYLATION REACTIONS; PHOSPHINE-LIGANDS; HECK REACTIONS; IONIC LIQUIDS; BOND;
D O I
10.1002/anie.201001787
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Simply reuse: Homogeneous palladium catalysts are effective and attractive tools for advanced organic synthesis (see example). Compound 1 belongs to a new class of ligands that enable recycling of the precious-metal catalyst directly from the reaction without any heterogenization. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:8988 / 8992
页数:5
相关论文
共 97 条
  • [81] Innovative solvent for two-phase catalysis - Ionic fluids
    Wasserscheid, P
    [J]. CHEMIE IN UNSERER ZEIT, 2003, 37 (01) : 52 - 63
  • [82] Wasserscheid P, 2000, ANGEW CHEM INT EDIT, V39, P3772, DOI 10.1002/1521-3773(20001103)39:21<3772::AID-ANIE3772>3.0.CO
  • [83] 2-5
  • [84] WASSERSCHEID P, 2000, CHEM INT, V39, P3773
  • [85] Wasserscheid P., 2002, IONIC LIQUIDS SYNTHE
  • [86] Wasserscheid P., 2000, ANGEW CHEM INT EDIT, V112, P3926, DOI DOI 10.1002/1521-3773(20001103)39:21<3772::AID-ANIE3772>3.0.CO
  • [87] 2-5
  • [88] Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides
    Watson, Donald A.
    Su, Mingjuan
    Teverovskiy, Georgiy
    Zhang, Yong
    Garcia-Fortanet, Jorge
    Kinzel, Tom
    Buchwald, Stephen L.
    [J]. SCIENCE, 2009, 325 (5948) : 1661 - 1664
  • [89] Room-temperature ionic liquids. Solvents for synthesis and catalysis
    Welton, T
    [J]. CHEMICAL REVIEWS, 1999, 99 (08) : 2071 - 2083
  • [90] Willis M. C., 2007, ANGEW CHEM, V119, P3470, DOI DOI 10.1002/ANGE.200605071