Growth and characterization of Ce-doped Ca3(BO3)2 crystals for neutron scintillator

被引:19
作者
Fujimoto, Yutaka [1 ,2 ]
Yanagida, Takayuki [1 ]
Tanaka, Hidehiko [1 ]
Yokota, Yuui [1 ]
Kawaguti, Noriaki [4 ]
Fukuda, Kentaro [1 ,4 ]
Totsuka, Daisuke [5 ]
Watanabe, Kenichi [6 ]
Yamazaki, Atsushi [6 ]
Yoshikawa, Akira [1 ,3 ]
机构
[1] Tohoku Univ, IMRAM, Aoba Ku, Sendai, Miyagi 9808577, Japan
[2] JSPS, Chiyoda Ku, Tokyo 1028472, Japan
[3] Tohoku Univ, NICHe, Aoba Ku, Sendai, Miyagi 9808579, Japan
[4] TOKUYAMA Corp, Shibuya Ku, Tokyo 1508383, Japan
[5] NIHON KESSHO KOGAKU CO LTD, Tatebayashi Gunma, Japan
[6] Nagoya Univ, Chikusa Ku, Nagoya, Aichi 4648603, Japan
关键词
Czochralski method; Borates; Scintillator materials; Scintillators; SINGLE-CRYSTALS; LAB3O6; PURE;
D O I
10.1016/j.jcrysgro.2010.10.189
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Single crystals of undoped and Ce3+-doped Ca-3(BO3)(2) (CBO) are grown by the Czochralski (CZ) method with an RF heating system. Undoped CBO crystal has high transmittance in the 190-900 nm wavelength range, while the absorption bands were observed around 275 and 350 nm due to the transition from the 4f ground state levels of F-2(5/2) and F-2(7/2) to Ce3+ 5d excited state in Ce3+-doped one. The photoluminescence spectrum of Ce3+-doped CBO crystal showed strong emission band around 400 nm under both 275 and 350 nm excitation due to the 5d-4f transition of Ce3+. In the measurement of pulse height spectra under Am-241 5.5 MeV alpha-ray excitation, Ce3+-doped CBO showed higher energy resolution compared with that of crystal grown by the micro-pulling down (mu-PD) method. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:784 / 787
页数:4
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