A Porous and Stable Porphyrin Metal-Organic Framework as an Efficient Catalyst towards Visible-Light-Mediated Aerobic Cross-Dehydrogenative-Coupling Reactions

被引：20
|
作者：
Liu, Jiewei [1 ,2 ,4 ]
Zhang, Kun [1 ]
Chen, Zhiyao [3 ]
Wei, Zhang-Wen [3 ]
Zhang, Li [3 ]
机构：
[1] Wuyi Univ, Sch Biotechnol & Hlth Sci, Jiangmen 529020, Peoples R China
[2] Int Healthcare Innovat Inst Jiangmen, Jiangmen 529040, Peoples R China
[3] Sun Yat Sen Univ, Sch Chem, Guangzhou 510275, Peoples R China
[4] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2020年 / 15卷 / 07期
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
porphyrin metal-organic frameworks; aerobic cross dehydrogenative coupling; carbon-phosphorus coupling; heterogeneous catalysis; superoxide radical anion; ACTIVE CU2+ SITES; HIGHLY EFFICIENT; C-C; SELECTIVE PHOTOOXIDATION; PHOTOREDOX CATALYSIS; TERTIARY-AMINES; WATER; MOF; NANOPARTICLES; PHOTOCATALYST;
D O I：
10.1002/asia.201901697
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Porphyrin metal-organic frameworks (PMOFs) are emerging as heterogeneous photocatalysts owing to the well-designed frameworks incorporated with powerful light-harvesting porphyrin chromophores. The porous and stable framework Ir-PCN-224 (which is also denoted as Ir-PMOF-1), which has been prepared by the self-assembly of Ir(TCPP)Cl (TCPP=tetrakis(4-carboxyphenyl)porphyrin) and ZrCl4, is reported herein to be efficient for the aerobic cross-dehydrogenative carbon-phosphorus coupling reaction, giving rise to a high turn-over number (TON) of up to 17200 under visible light irradiation (lambda >= 420 nm). Electron paramagnetic resonance (EPR) experiments disclose that the active species might be the superoxide radical anion (O-2(.-)). Additionally, the intermediate imine cation has been detected by high-resolution mass spectrometry (HRMS).
引用
收藏
页码：1118 / 1124
页数：7
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