Enhanced photocatalytic activity of N-doped TiO2 deposited on carbon fibers

被引:0
作者
Shang, Xili [1 ]
Li, Zhenyu [2 ]
Liu, Meiling [2 ]
Li, Changhai [1 ,2 ]
机构
[1] Binzhou Univ, Dept Chem Engn, Binzhou 256603, Peoples R China
[2] Changchun Univ Technol, Sch Chem Engn, Changchun 130012, Jilin, Peoples R China
基金
中国国家自然科学基金;
关键词
Doped; TiO2; Carbon fiber; Photocatalytic; HYDROTHERMAL SYNTHESIS; ONE-STEP; FE; DEGRADATION; POLLUTANTS; TITANIA; ADSORPTION; COMPOSITE; MECHANISM; CATALYSTS;
D O I
10.5004/dwt.2017.20887
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
N-doped TiO2 were successfully deposited on the surface of carbon fibers (CFs) by the sol-gel method. The synthesized samples show much higher adsorption capacity and photocatalytic activity for the degradation of Rhodamine B than the pure TiO2 under visible light irradiation. The doped N can further enhance the photocatalytic activity of TiO2 due to the significant synergistic effect between TiO2 and N, which can introduce intermediate level between the conduction band and valence band of TiO2, thus decreasing the band gap values effectively. Moreover, the deposition of doped TiO2 on CFs can promote the transfer and separation of photoproduction carriers, improving the adsorption capability of the catalyst and facilitating the recovery of catalyst. Meanwhile photocatalytic activity of the catalyst is reproducible which demonstrates excellent stability and recyclability factors, which are crucial for practical application.
引用
收藏
页码:153 / 159
页数:7
相关论文
共 36 条
[1]   Silver-modified titanium dioxide thin films for efficient photodegradation of methyl orange [J].
Arabatzis, IM ;
Stergiopoulos, T ;
Bernard, MC ;
Labou, D ;
Neophytides, SG ;
Falaras, P .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 42 (02) :187-201
[2]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[3]   Mono- and bimetallic Rh and Pt NSR-catalysts prepared by controlled deposition of noble metals on support or storage component [J].
Buechel, Robert ;
Pratsinis, Sotiris E. ;
Baiker, Alfons .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 113 :160-171
[4]   Electrochemical performance of Pd and Au-Pd core-shell nanoparticles on surface tailored carbon black as catalyst support [J].
Celorrio, V. ;
Montes de Oca, M. G. ;
Plana, D. ;
Moliner, R. ;
Fermin, D. J. ;
Lazaro, M. J. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (08) :7152-7160
[5]   One-step template-free route for synthesis of mesoporous N-doped titania spheres [J].
Chi, Bo ;
Zhao, Li ;
Jin, Tetsuro .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (17) :6189-6193
[6]   Preparation, photocatalytic activity, and mechanism of Nano-TiO2 co-doped with nitrogen and iron (III) [J].
Cong, Ye ;
Zhang, Jinlong ;
Chen, Feng ;
Anpo, Masakazu ;
He, Dannong .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (28) :10618-10623
[7]   A review on plasmonic metal-TiO2 composite for generation, trapping, storing and dynamic vectorial transfer of photogenerated electrons across the Schottky junction in a photocatalytic system [J].
Devi, L. Gomathi ;
Kavitha, R. .
APPLIED SURFACE SCIENCE, 2016, 360 :601-622
[8]   Charge separation and catalytic activity of Ag@TiO2 core-shell composite clusters under UV-irradiation [J].
Hirakawa, T ;
Kamat, PV .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (11) :3928-3934
[9]   ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS [J].
HOFFMANN, MR ;
MARTIN, ST ;
CHOI, WY ;
BAHNEMANN, DW .
CHEMICAL REVIEWS, 1995, 95 (01) :69-96
[10]   Platinum nanoparticles supported on activated carbon fiber as catalyst for methanol oxidation [J].
Huang, Hui Xing ;
Chen, Shui Xia ;
Yuan, Chan'e .
JOURNAL OF POWER SOURCES, 2008, 175 (01) :166-174