Synthesis, structures and luminescence properties of 3d-4f heterometallic-organic frameworks (HMOFs) constructed from different copper halide clusters

被引：17

作者：

Zeng, Guang ^{[1
]}

Xing, Shanghua ^{[1
]}

Wang, Xiuru ^{[1
]}

Yang, Yulin ^{[1
]}

Xiao, Yang ^{[1
]}

Li, Zhenhua ^{[1
]}

Li, Guanghua ^{[1
]}

Shi, Zhan ^{[1
]}

Feng, Shouhua ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Coll Chem, Changchun 130012, Peoples R China

来源：

CRYSTENGCOMM | 2016年 / 18卷 / 23期

基金：

中国国家自然科学基金;

关键词：

TO-CRYSTAL TRANSFORMATION; COORDINATION POLYMERS; PHOTOLUMINESCENCE PROPERTIES; MECHANICAL FORCE; ION-EXCHANGE; TEMPERATURE; EMISSION; COMPLEXES; THERMOCHROMISM; PHOSPHORS;

D O I：

10.1039/c5ce02544c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four novel 3d-4f heterometallic-organic frameworks (HMOFs), namely [Gd-2(Cu2I2)(C6H4NO2)(6)(C3H7NO)(H2O)]center dot(C3H7NO) (1), [Gd-2(Cu4I4)(C6H4NO2)(6)(C3H7NO)(2)] (2), [Gd-2(Cu6I6)(C12H8NO2)(6)(C2H6O)(2)(H2O)(2)] (3) and [Gd-2(Cu8I8)(C12H8NO2)(6)(H2O)(4)]center dot 5(C4H8O2) (4), have been solvothermally synthesized and characterized. The four compounds incorporate Cu2I2, Cu4I4, Cu6I6 and Cu8I8 clusters in three-dimensional frameworks, respectively, and the influence of Ln(3+) ions, copper halide clusters and ligands on the construction of the structures has been analyzed. The four compounds display four different emission colours. Interestingly, compound 3 responds to external mechanical force. After grinding, the fluorescence has been obviously quenched. Compound 4 displays a reversible luminescence behavior, accompanying the removal and recovery of the guest molecules in the channel.

引用

页码：4336 / 4342

页数：7

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