Design and construction of a microporous metal-organic framework based on the pillared-layer motif

被引:82
作者
Gao, Chaoying [1 ]
Liu, Shuxia [1 ]
Xie, Linhua [1 ]
Ren, Yuanhang [1 ]
Cao, Jianfang [1 ]
Sun, Chunyan [1 ]
机构
[1] NE Normal Univ, Key Lab Polyoxometallates Sci, Minist Educ, Changchun 130024, Peoples R China
关键词
D O I
10.1039/b704433j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A unique porous 3D metal - organic framework has been synthesized based on the insertion of heterogeneous pillars between 2D layers, the permanent porosity of which is confirmed by N-2 adsorption isotherm measurement.
引用
收藏
页码:545 / 547
页数:3
相关论文
共 28 条
[1]   LAYERED TITANATE PILLARED WITH ALUMINA [J].
ANDERSON, MW ;
KLINOWSKI, J .
INORGANIC CHEMISTRY, 1990, 29 (17) :3260-3263
[2]  
BRECK DW, 1974, ZEOLITE MOL SIEVES, P48
[3]  
Chen W, 2005, CHINESE J INORG CHEM, V21, P1901
[4]   PILLARING OF LAYERED TITANATES BY POLYOXO CATIONS OF ALUMINUM [J].
CHENG, SF ;
TANG, TC .
INORGANIC CHEMISTRY, 1989, 28 (07) :1283-1289
[5]   Synthesis, X-ray crystal structures, and gas sorption properties of pillared square grid nets based on paddle-wheel motifs: Implications for hydrogen storage in porous materials [J].
Chun, H ;
Dybtsev, DN ;
Kim, H ;
Kim, K .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (12) :3521-3529
[6]   Rigid and flexible: A highly porous metal-organic framework with unusual guest-dependent dynamic behavior [J].
Dybtsev, DN ;
Chun, H ;
Kim, K .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (38) :5033-5036
[7]   Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].
Eddaoudi, M ;
Kim, J ;
Rosi, N ;
Vodak, D ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2002, 295 (5554) :469-472
[8]   Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].
Eddaoudi, M ;
Moler, DB ;
Li, HL ;
Chen, BL ;
Reineke, TM ;
O'Keeffe, M ;
Yaghi, OM .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330
[9]   Crystal engineering of NLO materials based on metal-organic coordination networks [J].
Evans, OR ;
Lin, WB .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522
[10]   A multifunctional metal-organic open framework with a bcu topology constructed from undecanuclear clusters [J].
Fang, Qian-Rong ;
Zhu, Guang-Shan ;
Jin, Zhao ;
Xue, Ming ;
Wei, Xiao ;
Wang, De-Jun ;
Qiu, Shi-Lun .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (37) :6126-6130