Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites

被引：15

作者：

Carrasco, Mario ^{[2
]}

Faust, Michelle ^{[1
]}

Peloso, Riccardo ^{[2
]}

Rodriguez, Amor ^{[2
]}

Lopez-Serrano, Joaquin ^{[2
]}

Alvarez, Eleuterio ^{[2
]}

Maya, Celia ^{[2
]}

Power, Philip P. ^{[1
]}

Carmona, Ernesto ^{[2
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

[2] Univ Seville, CSIC, Dept Quim Inorgan, IIQ, Seville 41092, Spain

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 33期

基金：

美国国家科学基金会;

关键词：

METAL-METAL DISTANCES; TRANSITION-METAL; MULTIPLE BONDS; CHROMIUM; TERPHENYL; COMPOUND; CR; MOLYBDENUM; KINETICS; LENGTHS;

D O I：

10.1039/c2cc30394a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New quadruply bonded dimolybdenum complexes of the terphenyl ligand Ar-Xyl2 (Ar-Xyl2 = C6H3-2,6-(C6H3-2,6-Me-2)(2)) have been prepared and structurally characterized. The steric hindrance exerted by the Ar-Xyl2 groups causes the Mo atoms to feature unsaturated four-coordinate structures and a formal fourteen-electron count.

引用

页码：3954 / 3956

页数：3

共 38 条

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