Crystal structure of bis[tris(ethylenediamine)cobalt(III)] pentaoxalatocobaltate(II) tetrahydrate, [Co(C2H8N2)3]2[Co2(C2O4)5] • 4H2O

被引:1
作者
Kang, Jaeun [1 ]
Pyo, Seungmoon [1 ]
Yun, Hoseop [2 ,3 ]
Do, Junghwan [1 ]
机构
[1] Konkuk Univ, Dept Chem, Seoul 147701, South Korea
[2] Ajou Univ, Div Energy Syst Reseach, Suwon 441749, South Korea
[3] Ajou Univ, Dept Chem, Suwon 441749, South Korea
来源
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES | 2011年 / 226卷 / 03期
基金
新加坡国家研究基金会;
关键词
MAGNETIC-PROPERTIES; COMPLEXES;
D O I
10.1524/ncrs.2011.0158
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
C22H56Co4N12O24, triclinic, P (1) over bar (no. 2), a = 7.988(2) angstrom, b = 10.218(2) angstrom, c = 12.873(3) angstrom, alpha = 100.85(3)degrees, beta = 92.14(3)degrees, gamma = 93.57(3)degrees, V = 1028.6 angstrom(3), Z = 1, R-gt(F) = 0.037, wR(ref)(F-2) = 0.119, T = 293 K.
引用
收藏
页码:353 / 354
页数:2
相关论文
共 14 条
[1]   Bis and tris(oxalato) ferrate(III) complexes as precursors of polynuclear compounds [J].
Armentano, D ;
De Munno, G ;
Lloret, F ;
Julve, M .
CRYSTENGCOMM, 2005, 7 :57-66
[2]   Syntheses, crystal structures, and magnetic properties of the oxalato-bridged mixed-valence complexes [FeII(bpm)3]2[FeIII2(ox)5]•8H2O and FeII(bpm)3Na(H2O)2Fe(ox)3•4H2O (bpm=2,2′-bipyrimidine) [J].
Armentano, D ;
De Munno, G ;
Faus, J ;
Lloret, F ;
Julve, M .
INORGANIC CHEMISTRY, 2001, 40 (04) :655-660
[3]   Copper-linked hexaniobate lindqvist clusters-variations on a theme [J].
Bontchev, Ranko P. ;
Venturini, Eugene L. ;
Nyman, May .
INORGANIC CHEMISTRY, 2007, 46 (11) :4483-4491
[4]  
Brandenburg K., 2012, DIAMOND VISUAL CRYST
[5]   BOND-VALENCE PARAMETERS FOR SOLIDS [J].
BRESE, NE ;
OKEEFFE, M .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197
[6]   Charge transfer salts of tetrathiafulvalene derivatives with magnetic iron(III) oxalate complexes:: [TTF]7[Fe(ox)3]2•4H2O, [TTF]5[Fe2(ox)5]•2PhMe•2H2O and [TMTTF]4[Fe2(ox)5]• PhCN•4H2O (TMTTF = tetramethyltetrathiafulvalene) [J].
Coronado, E ;
Galán-Mascarós, JR ;
Gómez-García, CJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (02) :205-210
[7]   Hydrothermal synthesis and structure of a molybdenum(VI) phosphate cluster and a three dimensional cobalt molybdenum(V) phosphate [J].
He, X ;
Zhang, P ;
Song, TY ;
Mu, ZC ;
Yu, JH ;
Wang, Y ;
Xu, JN .
POLYHEDRON, 2004, 23 (13) :2153-2159
[8]   Synthesis, structure and magnetism of the oxalato-bridged chromium(III) complex [NBun4]4[Cr2(ox)5]•2CHCl3 [J].
Masters, VM ;
Sharrad, CA ;
Bernhardt, PV ;
Gahan, LR ;
Moubaraki, B ;
Murray, KS .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (03) :413-416
[9]   Three Co(III)-Fe(II) complexes based on hexacyanoferrates: Syntheses, spectroscopic and structural characterizations [J].
Matikova-Mal'arova, M. ;
Cernak, J. ;
Massa, W. ;
Varret, F. .
INORGANICA CHIMICA ACTA, 2009, 362 (02) :443-448
[10]   Molecular charge-transfer salt of BEDT-TTF [bis(ethylenedithio)tetrathiafulvalene] with the oxalate-bridged dimeric anion [Fe2(C2O4)5]4- [J].
Rashid, S ;
Turner, SS ;
Day, P ;
Light, ME ;
Hursthouse, MB .
INORGANIC CHEMISTRY, 2000, 39 (11) :2426-+